Abstract
Ultrathin, broadband microwave absorbing materials (MAMs) are crucial for weight-sensitive and space-constrained applications. This study introduces the electromagnetic frequency dispersion coefficient (EFDC), a synergistic dielectric-magnetic parameter that moves beyond conventional complex mechanisms. Our model directly links EFDC to microwave absorption (MA) performance, guiding the design of advanced MAMs. By optimizing EFDC, we achieved an ultra-wide effective absorption bandwidth (EAB) of 7.04 GHz at 1 mm and 9.28 GHz at 1.3 mm. Moreover, the temperature invariance of EFDC ensures consistent MA performance from 298 K to 473 K, despite the differing thermal responses of permittivity and permeability. This principle outlines a systematic design strategy for fabricating ultrathin and broadband MAMs, establishing a robust framework for developing high-attenuation absorbers suitable for complex frequency and thermal environments.
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References
Tao, J. et al. Phenolic multiple kinetics-dynamics and discrete crystallization thermodynamics in amorphous carbon nanostructures for electromagnetic wave absorption. Nat. Commun. 15, 10337 (2024).
Liu, X. et al. Modulating electromagnetic genes through Bi-phase high-entropy engineering toward temperature-stable ultra-broadband megahertz electromagnetic wave absorption. Nano Micro Lett. 17, 164 (2025).
Liu, A. et al. Asymmetric structural MXene/PBO aerogels for high-performance electromagnetic interference shielding with ultra-low reflection. Adv. Mater. 37, 2414085 (2025).
Sun, Z. et al. Anti-radar based on metasurface. Nat. Commun. 16, 7258 (2025).
Tao, J. et al. Anionic high-entropy doping engineering for electromagnetic wave absorption. Nat. Commun. 16, 3163 (2025).
Shu, J. C., Zhang, Y. L., Qin, Y. & Cao, M. S. Oxidative molecular layer deposition tailoring eco-mimetic nanoarchitecture to manipulate electromagnetic attenuation and self-powered energy conversion. Nano Micro Lett. 15, 142 (2023).
Zhang, Y. et al. Broadband and tunable high-performance microwave absorption of an ultralight and highly compressible graphene foam. Adv. Mater. 27, 2049–2053 (2015).
Qu, N. et al. 2D/2D coupled MOF/Fe composite metamaterials enable robust ultra-broadband microwave absorption. Nat. Commun. 15, 5642 (2024).
Wang, Z. Y. et al. Functional carbon springs enabled dynamic tunable microwave absorption and thermal insulation. Adv. Mater. 36, 2412605 (2024).
Lv, H. L. et al. Insights into civilian electromagnetic absorption materials: challenges and innovative solutions. Adv. Funct. Mater. 35, 2315722 (2024).
Cheng, J. Y. et al. Emerging materials and designs for low- and multi-band electromagnetic wave absorbers: the search for dielectric and magnetic synergy? Adv. Funct. Mater. 32, 2200123 (2022).
Zhao, Z. et al. Advancements in microwave absorption motivated by interdisciplinary research. Adv. Mater. 36, 2304182 (2024).
Hao, B. et al. Multiscale design of dielectric composites for enhanced microwave absorption performance at elevated temperatures. Adv. Funct. Mater. 35, 2423897 (2025).
Liu, X. et al. FeCoNiCr0.4CuX high-entropy alloys with strong intergranular magnetic coupling for stable megahertz electromagnetic absorption in a wide temperature spectrum. ACS Appl. Mater. Interfaces 14, 7012–7021 (2022).
Yang, J. M. et al. Construction of in situ grid conductor skeleton and magnet core in biodegradable poly (butyleneadipate-co-terephthalate) for efficient electromagnetic interference shielding and low reflection. Compos. Sci. Technol. 240, 110093 (2023).
Zhou, L. et al. Harnessing the electronic spin states of single atoms for precise electromagnetic modulation. Adv. Mater. 37, 2418321 (2025).
Cai, B. et al. Interface-induced dual-pinning mechanism enhances low-frequency electromagnetic wave loss. Nat. Commun. 15, 3299 (2024).
Wu, Z. et al. Dimensional design and core-shell engineering of nanomaterials for electromagnetic wave absorption. Adv. Mater. 34, 2107538 (2022).
Guo, Y. et al. Carbon nanocoils-assisted formation of tunable pore graphene aerogels for lightweight broadband microwave absorption, thermal insulation, and antifreeze devices. Small 21, 2412270 (2025).
Zhao, R. Z. et al. Highly anisotropic Fe3C microflakes constructed by solid-state phase transformation for efficient microwave absorption. Nat. Commun. 15, 1497 (2024).
Rozanov, K. N. Ultimate thickness to bandwidth ratio of radar absorbers. IEEE Trans. Antennas Propag. 48, 1230 (2000).
Ren, B. et al. Achieving broadband electromagnetic absorption at a wide temperature range up to 1273 K by metamaterial design on polymer-derived SiC-BN@CNT ceramic composites. Chem. Eng. J. 478, 147251 (2023).
Gai, L. et al. Compositional and hollow engineering of silicon carbide/carbon microspheres as high-performance microwave absorbing materials with good environmental tolerance. Nano Micro Lett. 16, 167 (2024).
Zhong, X. et al. Heterostructured BN@Co-C@C endowing polyester composites excellent thermal conductivity and microwave absorption at C band. Adv. Funct. Mater. 23, 13544 (2024).
He, M. et al. Excellent low-frequency microwave absorption and high thermal conductivity in polydimethylsiloxane composites endowed by hydrangea-like CoNi@BN heterostructure fillers. Adv. Mater. 36, 2410186 (2024).
Fang, G. et al. The elaborate design of multi-polarization effect by non-edge defect strategy for ultra-broad microwave absorption. Adv. Funct. Mater. 34, 2404532 (2024).
Zeng, X., Nie, T., Zhao, C., Gao, Y. & Liu, X. In situ exsolution-prepared solid-solution-type sulfides with intracrystal polarization for efficient and selective absorption of low-frequency electromagnetic wave. Adv. Sci. 11, 2403723 (2024).
Zhao, T. B., Lan, D., Jia, Z. R., Gao, Z. G. & Wu, G. L. Hierarchical porous molybdenum carbide synergic morphological engineering towards broad multi-band tunable microwave absorption. Nano Res. 17, 9845–9856 (2024).
Zhang, Q. L. et al. Constructing multiple heterogeneous interfaces in one-dimensional carbon fiber materials for superior electromagnetic wave absorption. Carbon 226, 119233 (2024).
Gao, Y. et al. Multifunction integration within magnetic CNT-bridged MXene/CoNi based phase change materials. eScience 4, 100292 (2024).
Zhang, K. L. et al. Tracking Regulatory Mechanism of Trace Fe on Graphene Electromagnetic Wave Absorption. Nano Micro Lett. 16, 66 (2024).
Yan, Y. F. et al. Phase engineering on MoS2 to realize dielectric gene engineering for enhancing microwave absorbing performance. Adv. Funct. Mater. 34, 2316338 (2024).
Shi, Y. Y. et al. Well-matched impedance of polypyrrole-loaded cotton non-woven fabric/polydimethylsiloxane composite for extraordinary microwave absorption. Compos. Sci. Technol. 197, 108246 (2020).
Song, W. L. et al. A universal permittivity-attenuation evaluation diagram for accelerating design of dielectric-based microwave absorption materials: A case of graphene-based composites. Carbon 118, 86–97 (2017).
Li, X. L. et al. Self-assembly core–shell graphene-bridged hollow MXenes spheres 3D foam with ultrahigh specific EM absorption performance. Adv. Funct. Mater. 28, 1803938 (2018).
Li, J. Z. et al. Permittivity genome: A new perspective on absorbing materials design. Chem. Eng. J. 503, 158398 (2025).
Liu, S. C. et al. Arousing effective attenuation mechanism of reduced graphene oxide-based composites for lightweight and high efficiency microwave absorption. Appl. Phys. Lett. 113, 083905 (2018).
Hou, Z. L., Gao, X. S., Zhang, J. Y. & Wang, G. S. A perspective on impedance matching and resonance absorption mechanism for electromagnetic wave absorbing. Carbon 222, 118935 (2024).
Lu, M. M. et al. Multiscale assembly of grape-like ferroferric oxide and carbon nanotubes: a smart absorber prototype varying temperature to tune intensities. ACS Appl. Mater. Interfaces 7, 19408–19415 (2015).
Hou, Z. X. et al. Reduced graphene oxide/silicon nitride composite for cooperative electromagnetic absorption in wide temperature spectrum with excellent thermal stability. ACS Appl. Mater. Interfaces 11, 5364–5372 (2019).
Lu, M. M. et al. Multi-wall carbon nanotubes decorated with ZnO nanocrystals: mild solution-process synthesis and highly efficient microwave absorption properties at elevated temperature. J. Mater. Chem. A 2, 10540–10547 (2014).
Wang, G. W. et al. Microwave absorption properties of flake-shaped Co particles composites at elevated temperature (293–673K) in X band. J. Magn. Magn. Mater. 456, 92–97 (2018).
Zhang, Y. H. et al. TiN nanofiber metacomposites for efficient electromagnetic wave absorption: Insights on multiple reflections and scattering effects. J. Mater. Sci. Technol. 233, 69–79 (2025).
Li, C. et al. Interface engineering of titanium nitride nanotube composites for excellent microwave absorption at elevated temperature. Nano Micro Lett. 16, 168 (2024).
Zhao, Y. M. et al. Simple synthesis of hollow CoFe carbon fiber composites with enhanced heterogeneous interfaces and impedance matching for broadband microwave absorption. J. Mater. Sci. Technol. 238, 178–190 (2025).
Li, Z. R. et al. Strategy-induced strong exchange interaction for enhancing high-temperature magnetic loss in high-entropy alloy powders. Adv. Funct. Mater. 35, 2507152 (2025).
Yu, M. et al. Yolk–shell Fe3O4@ZrO2 prepared by a tunable polymer surfactant assisted sol–gel method for high temperature stable microwave absorption. J. Mater. Chem. C 2, 7275–7283 (2014).
Yang, X. et al. Bio-inspired microwave modulator for high-temperature electromagnetic protection, infrared stealth and operating temperature monitoring. Nano Micro Lett. 14, 28 (2021).
Li, H. et al. High-frequency FeSiAl-based soft magnetic composites via simultaneously suppressed eddy and hysteresis losses. Nat. Commun. 16, 9563 (2025).
Acknowledgements
This work is financially supported by the National Natural Science Foundation of China (No. 22475065) (C.H.G.) and (No. 22305066) (C.P.L.).
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J.W.Z. and C.H.G. gave the research direction and contributed the basic framework and feasible technical route of the project. H.X.S. and Y.Z. conceived the idea, carried out the theoretical analysis and numerical simulations. H.X.S., Y.Z., M.L., and Z.H.C. built up the system and performed the experimental measurements. H.X.S. and C.P.L. performed the data analysis. J.W.Z. and C.H.G. provided the standard experimental site and equipment. H.X.S., C.P.L., and C.H.G. wrote the manuscript. All authors discussed the theoretical aspects and numerical simulations, interpreted the results, and reviewed the manuscript.
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Si, H., Zhang, Y., Li, M. et al. A synergistic design model for ultrathin broadband microwave absorbers using electromagnetic frequency dispersion coefficients. Nat Commun (2026). https://doi.org/10.1038/s41467-026-69591-x
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DOI: https://doi.org/10.1038/s41467-026-69591-x