Table 2 Changes in Si polymerization in tobermorite due to carbonation in different pH environments

From: Decalcification kinetics of calcium silicate hydrates: role of Al content, crystallinity, and initial pH

Tobermorite

Q4

Q3

Q2p

Q2b

Q1

−110.6 ppm

−99.3 ppm

−95.53 ppm

−93.1 ppm

−90.4 ppm

−85.5 ppm

−84.2 ppm

−79.4 ppm

Before carbonation

0%

0%

16.0%

3.0%

6.5%

24.4%

40.4%

9.8%

After carbonation

pH 9

56.2%

24.5%

3.8%

0%

3.5%

4.6%

7.4%

0%

pH 13

49.4%

37.7%

0%

0%

4.0%

0%

8.8%

0%

  1. 29Si NMRchemical shifts and integrated area (%) of the Qn species present in tobermorite samples before and after carbonation.