Extended Data Table 3 AlS/Ni(COD)2 (1)-mediated i-PP hydrogenolysis data under various conditions

From: Stable single-site organonickel catalyst preferentially hydrogenolyses branched polyolefin C–C bonds

  1. [a] Reaction conditions: Neat substrate, ~ 0.03 mol% Ni (~0.7 mg), 17 atm H2, 1500 rpm at 200 °C in Parr reactor with 25 mL internal volume.
  2. [b] commercial i-PP used.
  3. [c] conversion based on i-PP (PVC mass subtracted from solid fraction).
  4. [d] PTFE instead of PVC used.
  5. [e] AlS/Ni(COD)2 (1) was heated at 200 °C in presence of PVC.
  6. [f] AlS/NiCl instead of AlS/Ni(COD)2 was used.
  7. [g] AlS was used instead of AlS/Ni(COD)2 (1).
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