Introduction

The flowing medium gas lasers1 such as CO2 gas dynamic laser (λ = 10.6 µm)2, Hydrogen Fluoride–Deuterium Fluoride (HF-DF, λ = 2 0.7 − 3.4 µm3, and chemical oxygen iodine laser (COIL, λ = 1.315 µm4,5 emits in the infrared region. Among these lasers, COIL is scalable and offers wide range of applications with high efficiencies6,7,8,9 and good beam quality. Possibility of high-power, long-distance fiber delivery of the COIL laser makes it scalable to Mega Watt class level suitable for potential defense application. Figure 1 shows basic COIL schematic, which is typically a low pressure system operating at cavity pressures in range of 3–6 torr. In COIL, a reaction occurs between basic hydrogen peroxide (BHP) and chlorine gas (Cl2) to produce electronically excited singlet oxygen which is mixed with the lasing species stream i.e. (I2 + N2) inside the nozzle. The laser power is extracted at the laser cavity form the supersonic gas stream and the exhaust effluents are subsequently trapped in liquid nitrogen trap.

Figure 1
figure 1

Basic COIL schematic.

The optimum performance of COIL is governed by concentration of the lasing specie iodine, flow rates of nitrogen and chlorine, pressures in cavity, Pitot and plenum, iodine temperature, flow rates of circulating water in power measurement system (calorimeter) and BHP level. Monitoring and analysis of these critical gas dynamic parameters within desired accuracy and uncertainty limits is essential for precise control of COIL system. This is essential for characterization of several complex, obscure phenomenon occurring in the laser flow channel and to form requisite understanding for the same.

Uncertainty10,11,12 analysis is an effective process optimization tool in core research areas, which provides a good measure of realistic system performance and allows the user to identify key areas of improvement. In case of a COIL system it is obtained by evaluating parametric measurement uncertainty of both fundamental as well as derived parameters.

In order to evaluate errors and uncertainty in various measurements, International Organization for Standardization (ISO) has published the first edition of “Guide to the Expression of Uncertainty in Measurement (GUM)” [GUM11]. Also evaluation and expression of uncertainty is formally established for a wider range of measurements12,13,14. Uncertainty analysis of various systems has been reported by different researchers including diagnostics and wired data acquisition for COIL laser15 evaluation of expanded uncertainty using the LabVIEW in direct measurements16, error analysis of the data for evaluation of the performance of supersonic exhaust diffuser using scaled down models17, analysis of the projected errors of the chlorine utilization, water vapor pressure and singlet oxygen yield of the singlet oxygen chemical generator, equipped by the multichannel data acquisition system18, reliable uncertainty analysis and data evaluation for web based data acquisition system for poultry management19 and Type A and Type B uncertainty evaluation with improved methods20.

COIL (λ = 1315 nm) employs multidisciplinary technological areas for laser system realization. Development of customized data acquisition system is one of them. Typically, wired data acquisition systems15,21 have been mostly reported for operation of high power flowing medium laser systems on account of their reliability and proved track record. However, wired networks face issues pertaining to lack of accessibility and mobility. Further, they incur significant after-development trouble shooting costs due to various problems associated with cabled data acquisition system.

Hence, present development is focussed upon plausible alternative to the wired DAAS and explores wireless based technologies. This scheme of monitoring and control (data transmission) provides benefits in terms of reduction in size and involved installation/system costs, increased flexibility along with allowing simplified system deployments. Among the different wireless technologies available, Wi-Fi based systems are known to show better resistance to interference, reliable secure and better encryption and acceptable bit error rate of ~ 10–9. Also, it uses IEEE 802.11i security standard with 128 bit AES encryption. It also implements IEEE 802.1X, which is used for network authentication (Cranley, ITC). The systems also demonstrate high performance with regards to throughput, larger ranges, high data processing rates and high sampling rate (more bandwidth than ZigBee or Bluetooth). Further, power consumption of Wi-Fi based systems is low as compared to other such systems.

Hybrid data acquisition and analysis techniques utilize benefits of both wired and wireless technologies and have been successfully implemented in various practical real life scenarios like flight test networks22, smart grid applications24, monitoring of underground electricity substation25, monitoring of cultural heritage physical parameters26, greenhouse management27, turbine power generation system28. Hence, a hybrid DAAS appears to be an appropriate solution for use in a complex scenario such as flowing medium gas lasers and mitigating the shortfalls of a purely wired systems. Although researchers have developed data acquisition systems21,22,23,24,25,26,27,29,30 based on wired as well as hybrid techniques in different areas, but no one has reported detailed uncertainty analysis of data acquisition system for flowing laser to the best of our knowledge. The application of a hybrid DAAS for flowing medium gas laser and assessing its efficacy by employing methodical approach based on uncertainty evaluation, using GUM, forms the prime emphasis of the present work. The uncertainty analysis for flowing gas lasers has been briefly discussed primarily pertaining to gas flow parameters15, however, no specific studies with detailed uncertainty analysis aimed for entire high power gas laser system has been reported to the best of our knowledge. Although, accepted GUM practices of determining Type-A and Type-B uncertainties, relative uncertainties of derived parameters and overall combined uncertainty have been utilized, however the application of these concepts to a contemporary high power laser system makes it intricate primarily because similar analysis has not been largely reported in open literature.

In order to achieve realistic performance of COIL, a customized 150 channel hybrid concept-based Data Acquisition and Analysis System (DAAS) has been developed for remote operation of laser31,32,33. A structured approach utilizing detailed uncertainty evaluation has been used for ascertaining the effectiveness of the alternative DAAS system.

Overall operation of COIL laser generation process occurs within seconds (~ 10 s). Therefore, manual operation for such critical, complex and high end laser system is not viable. This is achieved by developed COIL DAAS, having 64 channels (analog inputs, AI) for parameter acquisition, 64 channels (digital outputs, DO) for valves (solenoid valve, electro-pneumatic valve, slit valve etc.) operation, 5 channels (analog outputs, AO) for gas feed and 17 channels (digital inputs, DI) for status monitoring of various valves/actuators. The parameter (variable) acquisition and analysis during the laser operation is an integral part of any data acquisition and analysis system pertaining to the safe sequential operation, required for successful laser operation. The focus primarily is to examine the efficacy of developed DAAS for multi variable, flowing medium COIL laser system.

Since gas laser systems, including COIL, are inherently complex involving several chemical processes, the system predictability and reliability becomes extremely subjective. In order to achieve repeatable optimal gas laser functioning for potential laser battlefield applications it is essential to characterize the uncertainty in laser functioning in terms of measurable macroscopic variables (primary/derived). It is in this context that a detailed uncertainty analysis and identification of most significant influences becomes critical. The uniqueness of the paper essentially lies in being able to identify these objective variables using the outlined uncertainty analysis. Further, it is quite evident that the control of these major influencing parameters is viable through custom DAAS instead of attempting to control the subtle chemical phenomenon occurring inside the laser flow field. Also, from application point of view this will enable in accurate prediction of scale of power utilized to beam potential targets producing soft kill/ hard kill and disabling target scenarios.

The analysis has been carried out by breaking down the system into direct parameter (pressure, temperature) and derived parameter (Flow rates, Gain etc.) measurement variables.

The temporal variation of most influencing variable (pressure) have been recorded in real time at various critical locations including Singlet Oxygen Generator (SOG), Cavity, Pitot, Plenum and gas/reagent flow systems. It enhances the decision making capability of the methodological approach and emerges out as an efficacious improvement tool for the measurement uncertainty evaluation.

The effects of the random sources are estimated by means of a multiple readings method and statistical approach (Type-A method for uncertainty estimation). On the other hand, uncertainty in observations other than repeated observations, Type-B uncertainty evaluation is carried out based on previous experiences and available information other than Type-A. Both the Type-A and Type-B uncertainties are combined to evaluate actual uncertainty and are referred as combined uncertainty. Relative uncertainty is defined either as measurement compared to the size of the measurement or as a percentage of the parameter under observation. The uncertainty, which results within the required samples percentage limit (confidence interval) is represented by the expanded uncertainty and is obtained by multiplying combined uncertainty by the coverage factor.

Systems description

COIL is a short operating duration (~ 10 s) laser with subsystems distributed over a large area with significant physical distances thereby rendering manual operation infeasible. It also utilizes toxic and hazardous chlorine, iodine and BHP during its operation. Therefore, in order to operate COIL laser remotely with safety, development of a customized DAAS is of prime importance.

DAAS architecture

A 150 channel DAAS comprising of 64 analog inputs (AI), 64 digital outputs (DO), 5 analog outputs (AO) and 17 digital inputs (DI) has been developed31. Main subsystems of developed DAAS are viz., (i) Sensor signal acquisition, (ii) Gas flow control/Switching control and (iii) Control and communication module. The block diagram of DAAS architecture is shown in Fig. 2a.

Figure 2
figure 2

(a) Block diagram of DAAS architecture. (b) Developed DAAS.

Sensor signal acquisition subsystem is responsible for acquiring different parameters such as temperature, pressure, flow rates and reagent level at different subsystems of COIL laser in analog input form (AI). It is also responsible for providing feedback with regards to status of various valves, chiller and other critical control modules of laser system in digital input form (DI).

Gas flow control/switching control (AO/DO) provides regulated gas supply to COIL system and is responsible for switching control of valves like solenoid valve/electro- pneumatic valve, mixer and chiller during laser finings for safe operation. Control and communication system comprises of Controller ARK 1122C, serial device server EKI-1361, router and display and control device with application software. Figure 2b shows actual developed DAAS hardware system for COIL.

DAAS has been configured using a 16 bit multifunction card USB 4716 (range 0–10 V). It has 16 single-ended or 8 differential channels AI, 2 channels of AO, 8 TTL channels of DI, 8 TTL channels of DO. Signal conditioner (S/C, Advantech 3014) provides optical isolation for protecting signals from harmful effects of ground loop, motor noise and other interferences. The features of the sensors employed in DAAS for COIL operation are listed in Table 1.

Table 1 Features of the sensors/detectors used in COIL operation using DAAS.

LabVIEW based software demonstration of DAAS

A LabVIEW platform based software program has been developed along with graphical user interfaces (GUI) for user friendly control and operation. Display and control device with application software is responsible for processing and execution of the program, display of various parameters indicating the real time status of different subsystems on the user interface. Eight GUIs have been developed for real time monitoring and control of different subsystem of COIL. A typical GUI for iodine evaporator module showing provisions for display of several pressures, temperatures, status of valve and their corresponding control is depicted in Fig. 3.

Figure 3
figure 3

GUI for iodine evaporator system.

Uncertainty analysis: methodology

The assessment of parameters with statistical theory is termed as Type A evaluation (obtained from frequency distributions), while assessment by any other means is termed as Type B evaluation (obtained from priori distribution)10,11,12,13,14. The various aspects of uncertainty analysis and computation of overall system uncertainty have been discussed in the present section. This mainly consists of estimating standard uncertainties attributable to direct sensor measurement, their relative uncertainties and similar uncertainty determinations for derived parameters. Subsequently, based on individual parametric uncertainties the variation in overall system performance is ascertained. It has been assumed that the variables in all the equations are independent and uncorrelated. Hence, a sum of squares method is used for all uncertainty calculations [GUM].

Uncertainty analysis for sensors data (including fundamental parameters)

Figure 4 shows sensor connection scheme with signal conditioner ADAM 3014 used for pressure, level and flow measurement channels. Output of the sensors (except temperature sensor) is 4–20 mA, which is converted into voltage signal using 301 Ω resistance. Hence, the input signal to ADAM 3014 is voltage signal. Detailed uncertainty evaluation has been carried out taking into account the potential uncertainties associated with each module in the line of sequence from sensor to display and control device for fundamental parameters by using statistical approach.

Figure 4
figure 4

Sensor connection with signal conditioner.

Propagation of uncertainty for different sensors (pressure, temperature, flow rate, level etc.) and DAAS signal cards (ADAM 3014, USB 4716 and ADAM 4118) is achieved using Type-B uncertainty method \(u_{B} \left( {x_{i} } \right)\). This is evaluated by using accuracies (from manufacturers specifications) of all sensors and DAAS cards for parametric measurement at different subsystems (Iodine Evaporator, Nozzle, Cavity, Pitot, Plenum etc.) of flowing medium COIL laser. Overall error is evaluated by taking RSS of all errors during sensor signal processing.Evaluation of standard uncertainty for each parameter measurement is listed in Table 2.

Table 2 Evaluation of Standard uncertainty \(u_{B} \left( {x_{i} } \right)\) by Type B method.

In order to achieve successful lasing in COIL, typical operating pressure inside cavity must lie within 263.1–658 Pa (2–5, torr), which is working pressure (in cavity) in COIL laser and optimum for laser extraction achieved after supersonic expansion in the nozzle. Hence, focus is limited only in the range of (263.1–658) Pa. Iodine supply temperature (Lasing medium in COIL) is (353 ± 5) K for optimum performance of the COIL system.

Type- A uncertainty evaluation, \(u_{A} \left( {x_{i} } \right)\)is based upon a sample of data and sample size of 1 kSamples/s/channel (using Signal Conditioner ADAM 3014 and USB 4716) and 12 samples/s/channel (using ADAM 4118) recorded for pressure and temperature respectively. Detailed computations of standard uncertainty and relative uncertainty have been carried out for both pressure and temperature (within desired limits of operation) and are summarized in Table 3.

Table 3 Standard uncertainty, \(u_{A} \left( {x_{i} } \right) = \frac{S}{\sqrt n }\) and Relative uncertainty, u (r) in cavity pressure and iodine temperature measurement.

Mean value of multiple readings (X) is evaluated as: \(\left( {X = {{\sum\nolimits_{i = 1}^{n} {X_{i} } } \mathord{\left/ {\vphantom {{\sum\nolimits_{i = 1}^{n} {X_{i} } } n}} \right. \kern-\nulldelimiterspace} n}} \right)\) and standard deviation (S) is evaluated as: \(\left( {S = \sqrt {{\raise0.7ex\hbox{${\sum\nolimits_{i = 1}^{n} {\left( {X_{i} - X} \right)^{2} } }$} \!\mathord{\left/ {\vphantom {{\sum\nolimits_{i = 1}^{n} {\left( {X_{i} - X} \right)^{2} } } {n - 1}}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${n - 1}$}}} } \right)\).

Uncertainty analysis of computed parameters

Uncertainty analysis of derived parameters35 is evaluated using functional relationship between derived and fundamental parameters. Assume that a derived parameter y is denoted by “Eq. (1)”,

$$y = f \left( {x_{1,} x_{2,} x_{3, \ldots } x_{N} } \right)$$
(1)

Uncertainty component in y due to the uncertainty in component x is expressed as “Eq. (2)”,

$$u(y_{i} ) = \left( {{\raise0.7ex\hbox{${\partial y}$} \!\mathord{\left/ {\vphantom {{\partial y} {\partial x_{i} }}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${\partial x_{i} }$}}} \right)u\left( {x_{i} } \right)$$
(2)

where, \(\left( {{\raise0.7ex\hbox{${\partial y}$} \!\mathord{\left/ {\vphantom {{\partial y} {\partial x_{i} }}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${\partial x_{i} }$}}} \right)\) is the sensitivity in measurement of parameter xi.

Combined uncertainty of y for two dependent correlated input quantities xi and xjaccording to the GUM is presented as “Eq. (3A)”.

$$u^{2} (y) = \sum\nolimits_{i = 1}^{N} {\sum\nolimits_{j = 1}^{N} {\frac{\partial f}{{\partial x_{i} }}} } \frac{\partial f}{{\partial x_{j} }}u(x_{i} ,x_{j} ).$$
(3A)

With the assumption of that all the fundamental parameters are independent and uniformly distributed, “Eq. (3A)” can be rewritten as the Root Sum Square (RSS) of individual uncertainty components- “Eq. (3B)”,

$$u(y) = \sqrt {\sum\nolimits_{i = 1}^{N} {u\left( {y_{i} } \right)}^{2} } = \sqrt {\sum\nolimits_{i = 1}^{N} {\left[ {({\raise0.7ex\hbox{${\partial y}$} \!\mathord{\left/ {\vphantom {{\partial y} {\partial x_{i} }}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${\partial x_{i} }$}})u\left( {x_{i} } \right)} \right]^{2} } } ,$$
(3B)

where, u(xi) is uncertainty evaluated by Type A (by statistical means) or standard Type B (by any other means) and Relative uncertainty is expressed as “Eq. (4)”,

$$u\left( r \right) = {\raise0.7ex\hbox{${u\left( y \right)}$} \!\mathord{\left/ {\vphantom {{u\left( y \right)} y}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{$y$}} = \sqrt {\sum\nolimits_{i = 1}^{N} {\left[ {{{u\left( x \right)_{i} } \mathord{\left/ {\vphantom {{u\left( x \right)_{i} } {x_{i} }}} \right. \kern-\nulldelimiterspace} {x_{i} }}} \right]^{2} } } .$$
(4)

The relative uncertainty of various derived parameters such as flow rates for various buffer gases, chlorine and iodine concentration have been considered for evaluation using relative uncertainty u(r) methodology.

Nitrogen is used both as primary and secondary buffer gas in COIL. Primary buffer gas is mixed with singlet oxygen flow for reducing singlet oxygen self-quenching. Secondary buffer gas is used for mixing nitrogen with iodine. Chlorine is used for generation of singlet oxygen. Iodine is lasing specie or active medium in COIL. The laser performance is governed by flow rates of these gases during operation. The uncertainty in orifice diameter is governed by the accuracy of the measuring device, which in the present case is a Vernier caliper with a resolution (∆d0) of 0.02 mm.

Hence, uncertainty in area uA is 3.1 × 10–10 m2, [By employing, {(π/4) × (∆d0)2}].

The orifice flow rate is governed by following relation, “Eq. (5)”, for choked flow condition operation of the orifice applicable in cases of primary and secondary nitrogen flows as well as chlorine flow,

$$\mathop m\limits^{.} = \sqrt {{\raise0.7ex\hbox{$\gamma $} \!\mathord{\left/ {\vphantom {\gamma R}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{$R$}}} \left\{ {{\raise0.7ex\hbox{${P_{0} A}$} \!\mathord{\left/ {\vphantom {{P_{0} A} {\sqrt {T_{0} } }}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${\sqrt {T_{0} } }$}}} \right\}C_{d} \left[ {{\raise0.7ex\hbox{$2$} \!\mathord{\left/ {\vphantom {2 {\gamma + 1}}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${\gamma + 1}$}}} \right]^{{{\raise0.7ex\hbox{${\gamma + 1}$} \!\mathord{\left/ {\vphantom {{\gamma + 1} {2\left( {\gamma - 1} \right)}}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${2\left( {\gamma - 1} \right)}$}}}} ,$$
(5)

wherein, is the mass flow rate of gases, γ is the specific heat ratio, P0 and T0 are stagnation pressure and stagnation temperature respectively, Cd is the discharge coefficient (0.93), A is the orifice area and R is the characteristic gas constant. Specific heat ratio for the gases is exactly known on the basis of the gas employed, for N2, it is 1.4 and for Cl2, it is 1.33 and so on so forth. They are a weak function of pressure and vary largely only at high temperatures they may vary as encountered in cases of combustion, thereby they can be easily treated as constant. The Cd indicates the average discharge coefficient, which has been measured by employing a dedicated orifice characterization setup which plots the flow vs. upstream pressure taking several reading for each pressure value and the straight line plot gives the average expected flow rate for each pressure value for which theoretical flow rate is known. The ratio of the two gives us the average coefficient of discharge. Hence, both the specific heat ratio and discharge coefficient are assumed to be constant. Relative uncertainty in flow rate of Primary N2 and Cl2 using (4) is obtained as “Eq. (6)”, by taking partial differentiation of “Eq. (5)”, and listed in Table 4,

$${{u\left( {\mathop m\limits^{.} } \right)} \mathord{\left/ {\vphantom {{u\left( {\mathop m\limits^{.} } \right)} {\mathop m\limits^{.} }}} \right. \kern-\nulldelimiterspace} {\mathop m\limits^{.} }} = \sqrt {\left( {{\raise0.7ex\hbox{${u\left( {P_{0} } \right)}$} \!\mathord{\left/ {\vphantom {{u\left( {P_{0} } \right)} {P_{0} }}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${P_{0} }$}}} \right)^{2} + \left( {{\raise0.7ex\hbox{${u\left( A \right)}$} \!\mathord{\left/ {\vphantom {{u\left( A \right)} A}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{$A$}}} \right)^{2} + \frac{1}{4}\left( {{\raise0.7ex\hbox{${u\left( {T_{0} } \right)}$} \!\mathord{\left/ {\vphantom {{u\left( {T_{0} } \right)} {T_{0} }}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${T_{0} }$}}} \right)^{2} } .$$
(6)
Table 4 Relative uncertainty in Primary N2, Secondary N2 and chlorine measurement.

Also, Molar flow rate variations may also be computed from “Eq. (7)”, by simplifying the “Eq. (5)”, using corresponding values of the constants as per the gases employed.

$$\begin{aligned} M_{c} & = \left\{ {{\raise0.7ex\hbox{${0.404P_{0} AC_{d} }$} \!\mathord{\left/ {\vphantom {{0.404P_{0} AC_{d} } {\sqrt {T_{0} } \left( {\frac{{0.028\,{\text{kg}}}}{{{\text{mol}}}}} \right)}}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${\sqrt {T_{0} } \left( {\frac{{0.028\,{\text{kg}}}}{{{\text{mol}}}}} \right)}$}}} \right\}{\raise0.7ex\hbox{${{\text{kg}}}$} \!\mathord{\left/ {\vphantom {{{\text{kg}}} {\text{s}}}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${\text{s}}$}} \\ & = \left\{ {{\raise0.7ex\hbox{${0.404P_{0} AC_{d} }$} \!\mathord{\left/ {\vphantom {{0.404P_{0} AC_{d} } {\sqrt {T_{0} } {{ \times }}0.028}}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${\sqrt {T_{0} } {{ \times }}0.028}$}}} \right\}{\raise0.7ex\hbox{${{\text{mol}}}$} \!\mathord{\left/ {\vphantom {{{\text{mol}}} {\text{s}}}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${\text{s}}$}} \\ \end{aligned}$$
(7)

The combined uncertainty, \(u\left( {M_{c} } \right)\), using “Eq. (3B)”:

$$u\left( {M_{c} } \right) = \sqrt {\frac{{\left\{ {\left( {{\raise0.7ex\hbox{${\partial M_{c} }$} \!\mathord{\left/ {\vphantom {{\partial M_{c} } {\partial P_{0} }}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${\partial P_{0} }$}}} \right)u_{{P_{0} }} } \right\}^{2} + \left\{ {\left( {{\raise0.7ex\hbox{${\partial M_{c} }$} \!\mathord{\left/ {\vphantom {{\partial M_{c} } {\partial T_{0} }}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${\partial T_{0} }$}}} \right)u_{{T_{0} }} } \right\}^{2} }}{{ + \left\{ {\left( {{\raise0.7ex\hbox{${\partial M_{c} }$} \!\mathord{\left/ {\vphantom {{\partial M_{c} } {\partial A}}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${\partial A}$}}} \right)u_{A} } \right\}^{2} }}}$$
(8)

Using partial derivatives in “Eq. (8)”, sensitivities are estimated as “Eq. (9)”

$${\raise0.7ex\hbox{${\partial M_{c} }$} \!\mathord{\left/ {\vphantom {{\partial M_{c} } {\partial P_{0} }}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${\partial P_{0} }$}} = {\raise0.7ex\hbox{${M_{c} }$} \!\mathord{\left/ {\vphantom {{M_{c} } {P_{0} }}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${P_{0} }$}},{\raise0.7ex\hbox{${\partial M_{c} }$} \!\mathord{\left/ {\vphantom {{\partial M_{c} } {\partial T_{0} }}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${\partial T_{0} }$}} = - {\raise0.7ex\hbox{${M_{c} }$} \!\mathord{\left/ {\vphantom {{M_{c} } {2T_{0} }}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${2T_{0} }$}},{\raise0.7ex\hbox{${\partial M_{c} }$} \!\mathord{\left/ {\vphantom {{\partial M_{c} } {\partial A}}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${\partial A}$}} = {\raise0.7ex\hbox{${M_{c} }$} \!\mathord{\left/ {\vphantom {{M_{c} } A}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{$A$}}.$$
(9)

Sensitivities in “Eq. (9)” are evaluated by putting values of Mc {from “Eq. (7)”} and values of P0, T0 and A (from Table 4). Combined uncertainty for secondary nitrogen, \(u_{{M_{c} }}\) is evaluated by using values of sensitivities and uncertainties of P0{u(P0)}, T0{u(T0)}, A{u(A)} (all from Table 4) and found to be, 1.1 × 10–2 mol/s. EPR provides controlled flow of secondary nitrogen by special software program developed using LabVIEW in developed DAAS. Relative uncertainty in secondary nitrogen flow rate measurement is estimated as: \({\raise0.7ex\hbox{${u\left( {M_{c} } \right)}$} \!\mathord{\left/ {\vphantom {{u\left( {M_{c} } \right)} {M_{c} }}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${M_{c} }$}}\) and listed in Table 4.

One of the most critical parameter influencing system performance is the uncertainty in measurement of the lasing species (iodine). Iodine is available in solid crystal form at room temperature (25 °C). Hence it is required to be heated to ~ 80 °C (353 K) in order to obtain uniform iodine vapors in iodine evaporator system for achieving proper mixing of singlet oxygen and iodine vapors occurs in the supersonic nozzle. The stabilization of vapors at indicated temperature is obtained by using pulse width modulation (PWM) based temperature stabilization (Proportional derivative controller, PID, Model no. MC-2438-201-000, Make: Max. Thermo, Taiwan). The precipitation of iodine during transport before reaching COIL system is prevented by employing heated secondary nitrogen passed through the iodine evaporation system to serve as the carrier. An optical absorption based process is used for iodine concentration measurement.

Iodine molar flow rate is expressed using the Beer Lambert law and the perfect gas law equation as “Eq. (10)”,

$$\dot{m}_{{I_{2} }} = \left\{ {\frac{{M_{c} kT_{0} }}{{\sigma _{v} L}}} \right\}\frac{{\ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)}}{{P_{{tot}} - \left( {\frac{{kT_{0} }}{{\sigma _{v} L}}} \right)\ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)}},$$
(10)

where I0 and Iv are light intensity in form of iodine detector signal without- upper lines and with iodine- bottom line (Fig. 5), σv is the absorption cross section (2.1 × 10–22 m2), L is the length of the iodine cell unit, k is the Boltzmann constant, T is the gas temperature, Ptot is the measured total pressure, Mc is the secondary N2 molar flow rate.

Figure 5
figure 5

Temporal variation of Iodine absorption signal.

The sensitivity calculations using partial differentiation as given in “Eq. (4)” are:

$$\frac{{\partial \mathop {m_{{I_{2} }} }\limits^{.} }}{{\partial M_{c} }} = \left\{ {\frac{{kT_{0} }}{{\sigma_{v} L}}} \right\}\frac{{\ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)}}{{P_{tot} - \left( {\frac{{kT_{0} }}{{\sigma_{v} L}}} \right)\ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)}} = \frac{{\mathop {m_{{I_{2} }} }\limits^{.} }}{{M_{c} }},$$
(11)
$$\begin{aligned} \frac{{\partial \mathop {m_{{I_{2} }} }\limits^{.} }}{{\partial T_{0} }} & = \left[ {\left\{ {\frac{{M_{c} k}}{{\sigma _{v} L}}} \right\}\frac{{\ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)}}{{P_{{tot}} - \left( {\frac{{kT_{0} }}{{\sigma _{v} L}}} \right)\ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)}} + \left\{ {\frac{{M_{c} kT_{0} }}{{\sigma _{v} L}}} \right\}\ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right) \times \left\{ {\frac{{ - 1}}{{\left\{ {P_{{tot}} - \left( {\frac{{kT_{0} }}{{\sigma _{v} L}}} \right)\ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)} \right\}^{2} }}} \right\} \times \left( {\frac{{ - k}}{{\sigma _{v} L}}} \right)\ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)} \right] \\ & = \frac{{\mathop {m_{{I_{2} }} }\limits^{.} }}{T}\left( {1 + \frac{{\mathop {m_{{I_{2} }} }\limits^{.} }}{{M_{c} }}} \right), \\ \end{aligned}$$
(12)
$$\frac{{\partial \mathop {m_{{I_{2} }} }\limits^{.} }}{{\partial L}} = \left[ \begin{gathered} \left\{ {\frac{{ - M_{c} kT_{0} }}{{\sigma _{v} L^{2} }}} \right\}\frac{{\ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)}}{{P_{{tot}} - \left( {\frac{{kT_{0} }}{{\sigma _{v} L}}} \right)\ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)}} + \left\{ {\frac{{M_{c} kT_{0} }}{{\sigma _{v} L}}} \right\}\ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)* \hfill \\ \left\{ {\frac{{ - 1}}{{\left\{ {P_{{tot}} - \left( {\frac{{kT_{0} }}{{\sigma _{v} L}}} \right)\ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)} \right\}^{2} }}} \right\} \times \left( {\frac{{ - kT_{0} }}{{\sigma _{v} }}} \right)\ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)\left( {\frac{{ - 1}}{{L^{2} }}} \right) \hfill \\ \end{gathered} \right] = - \frac{{\mathop {m_{{I_{2} }} }\limits^{.} }}{L}\left( {1 + \frac{{\mathop {m_{{I_{2} }} }\limits^{.} }}{{M_{c} }}} \right),$$
(13)
$$\frac{{\partial \mathop {m_{{I_{2} }} }\limits^{.} }}{{\partial P_{{tot}} }} = \left\{ {\frac{{M_{c} kT_{0} }}{{\sigma _{v} L}}} \right\}\ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right) \times \left\{ {\frac{{ - 1}}{{\left\{ {P_{{tot}} - \left( {\frac{{kT_{0} }}{{\sigma _{v} L}}} \right)\ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)} \right\}^{2} }}} \right\} = - \frac{{\mathop {m_{{I_{2} }} }\limits^{.} }}{{\left\{ {P_{{tot}} - \left( {\frac{{kT_{0} }}{{\sigma _{v} L}}} \right)\ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)} \right\}}},$$
(14)
$$\frac{{\partial \mathop {m_{{I_{2} }} }\limits^{.} }}{{\partial I_{0} }} = \left\{ {\frac{{M_{c} kT_{0} }}{{\sigma _{v} L}}} \right\} \times \left[ {\frac{{\left\{ {P_{{tot}} - \left( {\frac{{kT_{0} }}{{\sigma _{v} L}}} \right)\ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)} \right\}\frac{1}{{\left( {{\raise0.7ex\hbox{${I_{0} }$} \!\mathord{\left/ {\vphantom {{I_{0} } {I_{v} }}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${I_{v} }$}}} \right)}}\left( {\frac{1}{{I_{v} }}} \right) - \ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)\left( { - \frac{{kT_{0} }}{{\sigma _{v} L}}\frac{1}{{I_{0} }}} \right)}}{{\left\{ {P_{{tot}} - \left( {\frac{{kT_{0} }}{{\sigma _{v} L}}} \right)\ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)} \right\}^{2} }}} \right] = \frac{{\mathop {m_{{I_{2} }} }\limits^{.} }}{{I_{0} \ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)\,}}\left( {1 + \frac{{\mathop {m_{{I_{2} }} }\limits^{.} }}{{M_{c} }}} \right),$$
(15)
$$\begin{aligned} \frac{{\partial \mathop {m_{{I_{2} }} }\limits^{.} }}{{\partial I_{v} }} & = \left\{ {\frac{{M_{c} kT_{0} }}{{\sigma _{v} L}}} \right\} \times \left[ {\frac{{\left\{ {P_{{tot}} - \left( {\frac{{kT_{0} }}{{\sigma _{v} L}}} \right)\ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)} \right\} \times \left\{ {\frac{1}{{\left( {{\raise0.7ex\hbox{${I_{0} }$} \!\mathord{\left/ {\vphantom {{I_{0} } {I_{v} }}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${I_{v} }$}}} \right)}}\left( { - \frac{{I_{0} }}{{I_{{v^{2} }} }}} \right)} \right\} - \left\{ {\ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)\left( { - \frac{{kT_{0} }}{{\sigma _{v} L}}} \right)\frac{1}{{\left( {{\raise0.7ex\hbox{${I_{0} }$} \!\mathord{\left/ {\vphantom {{I_{0} } {I_{v} }}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${I_{v} }$}}} \right)}}\left( { - \frac{{I_{0} }}{{I_{{v^{2} }} }}} \right)} \right\}}}{{\left\{ {P_{{tot}} - \left( {\frac{{kT_{0} }}{{\sigma _{v} L}}} \right)\ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)} \right\}^{2} }}} \right] \\ & = - \frac{{\mathop {m_{{I_{2} }} }\limits^{.} }}{{I_{v} \ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)\,}}\left( {1 + \frac{{\mathop {m_{{I_{2} }} }\limits^{.} }}{{M_{c} }}} \right). \\ \end{aligned}$$
(16)

The experimental data for COIL system indicates that optimal iodine molar flow rate is 10 mmol s−1. By assuming negligible correlation among the variables in “Eq. (10)”,the combined uncertainty in iodine measurement using “Eq. (3B)” is calculated as “Eq. (17)”,

$$u\left( {\mathop {m_{{I_{2} }} }\limits^{.} } \right) = \sqrt {\left( {\frac{{\partial \mathop {m_{{I_{2} }} }\limits^{.} }}{{\partial M_{c} }}u\left( {M_{c} } \right)} \right)^{2} + \left( {\frac{{\partial \mathop {m_{{I_{2} }} }\limits^{.} }}{{\partial T_{0} }}u\left( {T_{0} } \right)} \right)^{2} + \left( {\frac{{\partial \mathop {m_{{I_{2} }} }\limits^{.} }}{\partial L}u\left( L \right)} \right)^{2} + \left( {\frac{{\partial \mathop {m_{{I_{2} }} }\limits^{.} }}{{\partial P_{tot} }}u\left( {P_{tot} } \right)} \right)^{2} + \left( {\frac{{\partial \mathop {m_{{I_{2} }} }\limits^{.} }}{{\partial I_{0} }}u\left( {I_{0} } \right)} \right)^{2} + \left( {\frac{{\partial \mathop {m_{{I_{2} }} }\limits^{.} }}{{\partial I_{v} }}u\left( {I_{v} } \right)} \right)^{2} } .$$
(17)

After substituting various sensitivity coefficients from “Eq. (11)” to “Eq. (16)” in “Eq. (17)” the combined uncertainty in iodine measurement was obtained as “Eq. (18)”:

$$u\left( {\mathop {m_{{I_{2} }} }\limits^{.} } \right) = \sqrt {\begin{array}{*{20}l} {\left\{ {\frac{{\mathop {m_{{I_{2} }} }\limits^{.} }}{{M_{c} }}u\left( {M_{c} } \right)} \right\}^{2} + \left\{ {\frac{{\mathop {m_{{I_{2} }} }\limits^{.} }}{T}\left( {1 + \frac{{\mathop {m_{{I_{2} }} }\limits^{.} }}{{M_{c} }}} \right)u\left( {T_{0} } \right)} \right\}^{2} + \left\{ { - \frac{{\mathop {m_{{I_{2} }} }\limits^{.} }}{L}\left( {1 + \frac{{\mathop {m_{{I_{2} }} }\limits^{.} }}{{M_{c} }}} \right)u\left( L \right)} \right\}^{2} + \left\{ { - \frac{{\mathop {m_{{I_{2} }} }\limits^{.} }}{{\left\{ {P_{{tot}} - \left( {\frac{{kT_{0} }}{{\sigma _{v} L}}} \right)\ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)} \right\}}}u\left( {P_{{tot}} } \right)} \right\}} \\ { + \left\{ {\frac{{\mathop {m_{{I_{2} }} }\limits^{.} }}{{I_{0} \ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)}}\left( {1 + \frac{{\mathop {m_{{I_{2} }} }\limits^{.} }}{{M_{c} }}} \right)u\left( {I_{0} } \right)} \right\}^{2} + \left\{ { - \frac{{\mathop {m_{{I_{2} }} }\limits^{.} }}{{I_{v} \ln \left( {\frac{{I_{0} }}{{I_{v} }}} \right)}}\left( {1 + \frac{{\mathop {m_{{I_{2} }} }\limits^{.} }}{{M_{c} }}} \right)u\left( {I_{v} } \right)} \right\}^{2} } \\ \end{array} }$$
(18)

Using all sensitivities from “Eq. (11)” to “Eq. (16)”, parametric uncertainties from Table 5 and detector output value for iodine absorption after amplification (gain = 50) from Fig. 5,

Table 5 Relative uncertainty in lasing specie (iodine) measurement.

\(u\left( {\mathop {m_{{I_{2} }} }\limits^{.} } \right)\) is estimated as 3 × 10–4 mol s−1. Relative uncertainty in iodine measurement is estimated as:

\({\raise0.7ex\hbox{${u\left( {\mathop m\limits^{.}_{{I_{2} }} } \right)}$} \!\mathord{\left/ {\vphantom {{u\left( {\mathop m\limits^{.}_{{I_{2} }} } \right)} {\mathop m\limits^{.}_{{I_{2} }} }}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${\mathop m\limits^{.}_{{I_{2} }} }$}}\) and is listed in Table 5.

Results and discussion

Standard (std.) uncertainty associated with the sensors and detector used in development of DAAS for COIL laser operation and functional optimization measuring fundamental parameters is evaluated in form of Type-B uncertainty. Combined std. uncertainty, \(u_{C} \left( y \right)\), is the actual measurement uncertainty and is estimated by the root sum square (RSS) of Type A and Type B uncertainties. It is given by \(u_{C} \left( y \right) = \sqrt {\left\{ {u_{B} \left( {x_{i} } \right)} \right\}^{2} + \left\{ {u_{A} \left( {x_{i} } \right)} \right\}^{2} }.\)

Expanded uncertainty U describes the uncertainty limits for enclosing the desired percentage of the population and with 95% confidence interval15 it is evaluated by, \(U_{95} = ku_{C} \left( y \right)\), multiplication of combined uncertainty and coverage factor kp. For k95, coverage value is 2.0. All the std. uncertainty, combined uncertainty, expanded uncertainty and relative combined std. uncertainty, \(u_{r} (\% ) = \left\{ {{{u_{C} \left( y \right)} \mathord{\left/ {\vphantom {{u_{C} \left( y \right)} A}} \right. \kern-\nulldelimiterspace} A}} \right\}{{ \times }}100\), have been evaluated for all significant influencing parameters and shown in Table 6. Figure 6 shows temporal pressure variations obtained at different locations of COIL laser system like Singlet Oxygen Generator (SOG), plenum, pitot and cavity during laser generation process (For conversion, 1 torr = 131.6 Pa).

Table 6 Expanded and relative uncertainty relevant to sensors/detectors.
Figure 6
figure 6

Temporal pressure variations during laser generation.

Real-time temporal pressure variations at various critical subsystem locations including SOG, plenum, Pitot, cavity and gas/liquid reagent were recorded in the form of a complex pressure plot. It justifies the usefulness of the developed hybrid DAAS system during COIL laser experiments. The sequential operation of various processes has been performed by the DAAS in order to maintain the cavity pressure in the range of 3–6 Torr during laser operation.

The involved complexity is evident from the pressure variation inside the SOG. The first rise in pressure is due to initiating primary nitrogen flow (at 5.3 s) (Ist hump) which effectively compensates chlorine flow (0.45 mol s−1) which is started at 7.4 s. At this time the primary flow rate drops from 1.5 to 1.0 mol s−1. The secondary nitrogen flow (0.5 mol s−1) carrying the lasing medium is initiated at nearly the same time leading to the second pressure rise (IInd hump).

The typical stable pressures achieved for SOG, Plenum, Pitot and Cavity are 32 torr, 17 torr, 12 torr and 5.5 torr respectively. In addition, the flow rates for primary Nitrogen and Chlorine also have been obtained directly in flow plots (under Graph GUI), Fig. 7. It clearly verifies the start of flow of Primary Nitrogen and Chlorine at 5.3 s and 7.4 s respectively.

Figure 7
figure 7

Temporal flow rate variation, flow rate (mol s−1) vs. time (s).

Relative uncertainty of all the derived parameters, degree of freedom,

$$v_{i} \approx \frac{1}{2}\left[ {\frac{{\Delta u\left( {x_{i} } \right)}}{{u\left( {x_{i} } \right)}}} \right]^{ - 2} \approx \frac{1}{2}\left[ {u\left( r \right)} \right]^{ - 2} ,$$

and their coverage factor (using t-distribution table) are listed in Table 7.

Table 7 Relative uncertainty in derived parameter measurement.

Overall uncertainty evaluation for the DAAS system

From the analyses of the various sources of uncertainty in DAAS used for COIL, employing both uncertainty and sensitivity of sensors, it is clear that it is viable to correctly examine the DAAS system performance and its efficacy. Since no direct relation exists between the sensor architecture, display and control device in development of DAAS, hence instead of Monte-Carlo method34 the GUM tool has been utilized11,35,36 for uncertainty analysis.

Detailed uncertainty analysis using both Type-A and Type-B methods have been carried out for fundamental as well as derived parameters relevant to COIL laser and summarized in Tables 4 and 6 respectively. It is clear that the combined uncertainty in both pressure and temperature acquisition using developed DAAS is nearly identical with Type-B uncertainty (i.e. influence of Type-A uncertainty is negligible). Hence, in order to avoid the effect of double count problem of uncertainty components, effect of Type-B uncertainty is considered as a prime component for evaluating combined uncertainty.

Relative combined std. uncertainty, U(total) for developed DAAS is evaluated19 as indicated as “Eq. (19)”:

$$U\left( {total} \right) = \sqrt {\left\{ {u\left( {r,\Pr ess} \right)} \right\}^{2} + \left\{ {u\left( {r,Temp} \right)} \right\}^{2} + \left\{ {u\left( {r,Level} \right)} \right\}^{2} + \left\{ {u\left( {r,EPR} \right)} \right\}^{2} + \left\{ {u\left( {r,Flow} \right)} \right\}^{2} + \left\{ {u\left( {r,Iodine} \right)} \right\}^{2} } = 8.3\% .$$
(19)

The quantification of U(total) for the system is critical in terms of assessing relative correctness (closeness) of the data indicated by the DAAS to the true values of critical parameters of the COIL system. In order to be able to accurately optimize a multidisciplinary system such as COIL involving high speed flow, it is imperative that overall uncertainty of the system is within 5–10% ranges. It is all the more essential as in COIL, subsystems are capable of producing significant mutual influences creating spiraling effect and rendering the system non functional since the operating band for such flow medium lasers is apparently quite narrow. Thus, a detailed assessment of U(total) is useful for optimal operation of complex gas laser system such as COIL. It is evident from the above calculations, Tables 6 and 7 that measurement uncertainty of developed DAAS is mainly governed by instabilities of pressure sensor. Hence performance of DAAS system is much more sensitive to changes in pressure sensor than changes in any other fundamental or derived parameter uncertainty. Hence, it underlines the need for careful selection of pressure sensor and its precise calibration to reduce U(total). The use of remote DAAS facilitates parametric and system uncertainty assessment by circumventing manual measurement/ observation and enabling carrying out repeated experimentation for generating exhaustive data.

Conclusion

A dedicated 150 channels (64AI, 64DO, 5AO, 17DI) DAAS has been designed and developed using LabVIEW application software to fulfill the operation, acquisition and analysis requirement of flowing medium high power (2.3 mol/s) COIL laser. Precise operational control of DAAS has been achieved using accurate and reliable data from the sensor system. This DAAS is used for various experiments of COIL laser and related technologies which proves its efficacy.

GUM algorithm approaches have been utilized for evaluation of uncertainty of the developed DAAS system. This would potentially provide significant insights for improving the developed system by determining detailed uncertainty for both fundamental as well as derived parameters. Based on the uncertainty analysis it is evident that Type-B uncertainty computation of standard uncertainty is more reliable than Type-A uncertainty. It is inferred that DAAS system performance is primarily governed by pressure sensor uncertainty. The pressures at different locations of COIL system are further controlled by the flow rates of different gas constituents like N2, Cl2 and I2. The laser power achieved is essentially the measure of overall system performance and the estimated total variation is 8.3%. More than 200 experiments were carried out successfully and controlled safe operation of high power COIL laser system was achieved by using the developed DAAS system after obtaining accurate and reliable data from the sensor/detector system. This enables prediction of overall system uncertainty potentially extendable to other similar laser systems involving subsystems with mutual interdependencies together being distributed over a significantly large laboratory space. To the best of our understanding, this is amongst the first attempt to report the uncertainty evaluation of a highly complex Chemical Oxygen Iodine Laser system.

Enhanced decision-making in optimizing a complex supersonic flowing medium gas laser has been achieved by developing a suitable hybrid DAAS. The existing approaches to uncertainty have been innovatively utilized to not only predict the overall system uncertainty but also the most crucial influencing parameter i.e. Pressure. This in a way presents a measure of the reliability of system performance in a battlefield scenario, enabling the prediction of the potential effect on the target reasonable precision.