Table 2 The contents of anthocyanins, phenolic acid, flavonols, polymeric procyanidins, and degree of polymerization in 14 cultivars of of highbush blueberry fruits [mg/100 g].

From: Biodiversity in nutrients and biological activities of 14 highbush blueberry (Vaccinium corymbosum L.) cultivars

Lp	Rt	UV–Vis	m/z	MS/MS	Compounds	Aurora	Bluecrop	Bluegold	Bonifacy	Bonus	Brigitta Blue	Chandler	Draper	Duke	Lateblue	Liberty	Nelson	Spartan	Toro
Anthocyanins
1	2.37	276, 522	465	303	Delphinidin 3-O-glucoside	162.48 ± 1.41*	41.85 ± 0.36	110.59 ± 0.96	130.29 ± 1.13	121.45 ± 1.06	115.98 ± 1.01	112.64 ± 0.98	119.52 ± 1.04	164.90 ± 1.43	176.07 ± 1.53	135.01 ± 1.17	76.37 ± 0.66	60.75 ± 0.53	109.06 ± 0.95
2	2.51	277, 522	465	303	Delphinidin 3-O-galactoside	6.53 ± 0.06	22.90 ± 0.20	5.69 ± 0.05	41.58 ± 0.36	42.26 ± 0.37	5.93 ± 0.05	49.90 ± 0.43	5.94 ± 0.05	6.27 ± 0.05	11.17 ± 0.10	6.23 ± 0.05	41.75 ± 0.36	35.73 ± 0.31	5.61 ± 0.05
3	2.72	277, 522	435	303	Delphinidin-3-O-arabinoside	88.45 ± 0.77	45.02 ± 0.39	85.21 ± 0.74	128.16 ± 1.12	87.02 ± 0.76	79.45 ± 0.69	98.27 ± 0.85	81.32 ± 0.71	107.84 ± 0.94	109.8 ± 0.96	106.31 ± 0.92	70.67 ± 0.61	52.13 ± 0.45	77.53 ± 0.67
4	2.95	276, 525	479	317	Petunidin 3-O-glucoside	84.87 ± 0.74	24.92 ± 0.22	67.66 ± 0.59	73.90 ± 0.64	53.02 ± 0.46	51.82 ± 0.45	57.06 ± 0.50	64.79 ± 0.56	95.78 ± 0.83	90.58 ± 0.79	74.74 ± 0.65	38.15 ± 0.33	28.83 ± 0.25	53.45 ± 0.46
5	3.09	278, 522	479	317	Petunidin 3-O-galactoside	14.14 ± 0.12	23.56 ± 0.20	14.62 ± 0.13	40.49 ± 0.35	40.65 ± 0.35	14.31 ± 0.12	47.00 ± 0.41	15.11 ± 0.13	17.80 ± 0.15	18.89 ± 0.16	17.51 ± 0.15	38.59 ± 0.34	28.85 ± 0.25	12.62 ± 0.11
6	3.27	279, 526	449	317	Petunidin 3-O-arabinoside	37.49 ± 0.33	20.39 ± 0.18	39.77 ± 0.35	53.75 ± 0.47	27.37 ± 0.24	29.29 ± 0.25	35.32 ± 0.31	35.51 ± 0.31	45.84 ± 0.40	43.75 ± 0.38	45.48 ± 0.4	23.89 ± 0.21	19.75 ± 0.17	29.97 ± 0.26
7	3.48	278, 526	493	331	Malvidin 3-O-glucoside	356.51 ± 3.10	94.39 ± 0.82	307.46 ± 2.67	367.64 ± 3.20	119.92 ± 1.04	126.03 ± 1.10	160.15 ± 1.39	281.46 ± 2.45	439.65 ± 3.82	397.78 ± 3.46	352.97 ± 3.07	101.56 ± 0.88	79.03 ± 0.69	208.57 ± 1.81
8	3.64	276, 527	493	331	Malvidin 3-O-galactoside	21.17 ± 0.18	57.07 ± 0.50	16.68 ± 0.15	100.60 ± 0.88	74.65 ± 0.65	15.02 ± 0.13	119.07 ± 1.04	16.82 ± 0.15	18.93 ± 0.16	32.96 ± 0.29	23.28 ± 0.20	79.59 ± 0.69	58.33 ± 0.51	13.88 ± 0.12
9	3.77	274, 527	507	303	Delphinidin3-O-(6ʺ-acetyl-glucoside)	nd**	12.13 ± 0.11	nd	25.27 ± 0.22	8.12 ± 0.07	nd	nd	nd	nd	nd	nd	15.71 ± 0.14	11.05 ± 0.10	nd
10	3.83	276, 527	463	301	Peonidin 3-O-glucoside	60.14 ± 0.52	34.55 ± 0.30	75.95 ± 0.66	86.34 ± 0.75	22.55 ± 0.20	29.40 ± 0.26	40.78 ± 0.35	58.94 ± 0.51	73.70 ± 0.64	67.81 ± 0.59	74.22 ± 0.65	23.87 ± 0.21	24.25 ± 0.21	42.61 ± 0.37
11	4	278, 529	521	317	Petunidin 3-O-(6ʺ-acetyl-glucoside)	nd	9.80 ± 0.09	11.05 ± 0.10	17.50 ± 0.15	9.22 ± 0.08	nd	nd	nd	nd	nd	nd	8.61 ± 0.07	9.68 ± 0.08	9.97 ± 0.09
12	4.2	278, 522	491	287	Cyanidin 3-O-(6ʺ-acetyl-glucoside)	nd	7.83 ± 0.07	nd	6.90 ± 0.06	5.66 ± 0.05	nd	nd	nd	nd	nd	nd	6.83 ± 0.06	5.11 ± 0.04	nd
13	4.32	352, 529	521	317	Petunidin 3-O-(6ʺ-acetyl-galactoside)	nd	13.68 ± 0.12	nd	19.96 ± 0.17	9.32 ± 0.08	nd	nd	nd	nd	nd	nd	12.95 ± 0.11	12.29 ± 0.11	8.13 ± 0.07
14	4.54	276, 529	535	331	Malvidin 3-O-(6ʺ-acetyl-glucoside)	nd	25.83 ± 0.22	44.55 ± 0.39	141.49 ± 1.23	15.98 ± 0.14	nd	nd	nd	nd	nd	nd	10.48 ± 0.09	15.71 ± 0.14	30.43 ± 0.26
15	4.85	277, 529	535	331	Malvidin 3-O-(6ʺ-acetyl-galactoside)	nd	41.94 ± 0.36	10.86 ± 0.09	119.64 ± 1.04	15.29 ± 0.13	nd	nd	nd	nd	nd	nd	25.83 ± 0.22	25.12 ± 0.22	9.92 ± 0.09
Phenolic acid
16	2.73	353	191	329	3-O-caffeoylquinic acid	329.14 ± 5.27	239.04 ± 3.82	228.93 ± 3.66	280.58 ± 4.49	135.20 ± 2.16	176.93 ± 2.83	209.46 ± 3.35	245.71 ± 3.93	144.26 ± 2.31	292.35 ± 4.68	181.20 ± 2.90	277.99 ± 4.45	192.85 ± 3.09	151.07 ± 2.42
Flavonols
17	3.68	253, 350	479	317	Myricetin 3-O-glucoside	8.63 ± 0.14	19.09 ± 0.31	12.33 ± 0.20	24.20 ± 0.39	17.07 ± 0.27	13.11 ± 0.21	28.47 ± 0.46	18.61 ± 0.3	20.99 ± 0.34	9.36 ± 0.15	4.23 ± 0.07	14.70 ± 0.24	11.68 ± 0.19	15.06 ± 0.24
18	4.07	255, 350	519	433, 301	Quercetin 3-O-(6″malonyl)-glucoside	4.49 ± 0.07	2.64 ± 0.04	6.99 ± 0.11	3.56 ± 0.06	1.28 ± 0.02	1.40 ± 0.02	2.57 ± 0.04	5.45 ± 0.09	6.23 ± 0.10	4.99 ± 0.08	5.82 ± 0.09	1.58 ± 0.03	1.36 ± 0.02	3.28 ± 0.05
19	4.12	253, 348	479	317	Myricetin 3-O-galactoside	nd	1.69 ± 0.03	nd	2.96 ± 0.05	3.51 ± 0.06	0.27 ± 0.001	3.03 ± 0.05	0.94 ± 0.02	1.40 ± 0.02	2.78 ± 0.04	3.23 ± 0.05	1.70 ± 0.03	0.97 ± 0.02	0.74 ± 0.01
20	4.27	255, 3550	609	301	Quercetin 3-O-rutinoside	30.12 ± 0.48	7.70 ± 0.12	10.84 ± 0.17	5.65 ± 0.09	10.43 ± 0.17	17.09 ± 0.27	0.79 ± 0.01	4.48 ± 0.07	0.29 ± 0,001	21.79 ± 0.35	38.20 ± 0.61	4.19 ± 0.07	1.65 ± 0.03	0.23 ± 0.001
21	4.33	255, 350	463	301	Quercetin 3-O-glucoside	86.23 ± 1.38	33.42 ± 0.53	24.45 ± 0.39	37.79 ± 0.60	23.33 ± 0.37	56.56 ± 0.9	52.42 ± 0.84	68.09 ± 1.09	65.63 ± 1.05	32.5 ± 0.52	17.67 ± 0.28	36.37 ± 0.58	36.98 ± 0.59	39.25 ± 0.63
22	4.46	255, 350	463	301	Quercetin 3-O-galactoside	21.7 ± 0.35	17.53 ± 0.28	9.50 ± 0.15	23.13 ± 0.37	8.39 ± 0.13	20.34 ± 0.33	8.75 ± 0.14	10.62 ± 0.17	8.19 ± 0.13	11.28 ± 0.18	16.14 ± 0.26	14.57 ± 0.23	7.19 ± 0.11	7.18 ± 0.11
23	4.64	255, 350	433	301	Quercetin 3-O-pentoside I	3.09 ± 0.05	0.07 ± 0.001	1.07 ± 0.02	0.31 ± 0.001	0.73 ± 0.01	0.18 ± 0.001	0.2 ± 0.001	0.08 ± 0.001	0.14 ± 0.001	4.72 ± 0.08	5.28 ± 0.08	0.24 ± 0.001	0.01 ± 0.001	1.10 ± 0.02
24	4.71	255, 350	609	301	Quercetin 3-O-rabinobioside	nd	3.01 ± 0.05	nd	1.72 ± 0.03	0.69 ± 0.01	3.19 ± 0.05	1.40 ± 0.02	1.58 ± 0.03	2.21 ± 0.04	1.09 ± 0.02	4.02 ± 0.06	2.94 ± 0.05	1.69 ± 0.03	0.19 ± 0.001
25	4.75	255, 350	433	301	Quercetin 3-O-pentoside II	18.30 ± 0.29	6.03 ± 0.10	3.83 ± 0.06	5.17 ± 0.08	3.13 ± 0.05	6.18 ± 0.1	9.91 ± 0.16	9.21 ± 0.15	9.19 ± 0.15	7.15 ± 0.11	3.95 ± 0.06	6.89 ± 0.11	5.66 ± 0.09	2.19 ± 0.04
26	4.83	255, 350	433	301	Quercetin 3-O-pentoside III	22.53 ± 0.36	3.05 ± 0.05	5.46 ± 0.09	0.60 ± 0.01	5.80 ± 0.09	2.87 ± 0.05	nd	0.82 ± 0.01	5.23 ± 0.08	13.70 ± 0.22	20.00 ± 0.32	5.94 ± 0.09	0.18 ± 0.001	7.56 ± 0.12
27	4.89	255, 350	447	301	Quercetin 3-O-rhamnoside	5.35 ± 0.09	4.39 ± 0.07	nd	1.53 ± 0.02	2.00 ± 0.03	0.15 ± 0.001	2.83 ± 0.05	3.28 ± 0.05	nd	5.28 ± 0.08	nd	4.34 ± 0.07	5.65 ± 0.09	0.58 ± 0.01
28	4.96	253, 350	623	315	Isorhamnetin 3-O-rutinoside	7.81 ± 0.12	4.25 ± 0.07	nd	3.64 ± 0.06	0.85 ± 0.01	2.00 ± 0.03	nd	0.99 ± 0.02	nd	1.26 ± 0.02	1.54 ± 0.02	1.04 ± 0.02	0.41 ± 0.01	2.46 ± 0.04
29	5.02	253, 350	447	315	Isorhamnetin 3-O-pentoside	56.95 ± 0.91	nd	12.69 ± 0.20	3.15 ± 0.05	10.90 ± 0.17	7.32 ± 0.12	0.40 ± 0.01	5.10 ± 0.08	1.89 ± 0.03	35.23 ± 0.56	51.53 ± 0.82	1.05 ± 0.02	0.92 ± 0.01	1.71 ± 0.03
30	5.14	255, 323	505	463, 301	Quercetin 3-O-(6ʺacetyl)-glucoside	4.61 ± 0.07	14.96 ± 0.24	4.72 ± 0.08	8.45 ± 0.14	4.77 ± 0.08	1.88 ± 0.03	3.53 ± 0.06	6.25 ± 0.10	6.46 ± 0.10	6.13 ± 0.10	7.93 ± 0.13	14.38 ± 0.23	2.34 ± 0.04	3.10 ± 0.05
Degree of polymerization (DP)						14.63	7.23	8.87	13.07	6.98	16.86	9.18	14.48	9.06	16.38	13.52	7.90	17.10	5.78
Polymeric procyanidins						3500.79 ± 30.46	2086.19 ± 18.15	4243.36 ± 36.92	2635.43 ± 22.93	2209.16 ± 19.22	2380.1 ± 20.71	3060.88 ± 26.63	2212.13 ± 19.25	2019.19 ± 17.57	4212.62 ± 36.65	2817.68 ± 24.51	3247.11 ± 28.25	2844.26 ± 24.75	2295.57 ± 19.97
Total of polyphenols						4931.53c	2918.90m	5354.26b	4391.38d	3089.71l	3156.79j	4104.81f.	3272.76i	3262.03i	5611.04a	4014.17g	4209.85e	3580.39h	3143.01k

*Mean values denoted by the same letter in the horizontal line do not differ statistically significantly at 0.05 according to Tukey’s test.
**nd, not identified.

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Table 2 The contents of anthocyanins, phenolic acid, flavonols, polymeric procyanidins, and degree of polymerization in 14 cultivars of of highbush blueberry fruits [mg/100 g].

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