Table 3 Comparative performance analysis of two Al purification processes.

From: Innovative vacuum distillation technology for preparing refined Al from Al–Mg alloy

Economic & technical indicators

VD process

Three-layer electrolysis refining process40,41

Al content in refined Al

99.9989%

Less than 99.996%

Al direct recovery efficiency

97.98%

95–98%

Behavior of Al and Mg

Al-Mg alloy → Refined Al + Elemental Mg

Al-Mg alloy → Refined Al + Mg2 + salts

Proportioning

Without additives

Electrolyte (Na3AlF6, NaCl, KCl, Na2CO3, K2CO3), graphite electrode

Energy consumption

Electricity < 4.60 kW·h/kg

Electricity > 16 kW·h/kg

Processing conditions

1373 K

993 K to 1073 K

Waste discharge

No discharge

Dust (fluorides), gas pollutants (SO2, CO2), smelting slag

Primary equipments

Vacuum resistance furnace

Al electrolytic cell + cathode + anode + vacuum ladle + dust collection equipments

Technological steps

VD

Proportioning + melting + slag discharging + electrolyte replenishment + cathode replacement + Al discharging