Fig. 8: Substrate scope of the photocatalytic isoperfluoropropylation of non-activated arenes.

Reaction conditions: 2c (0.2 mmol, 1.0 equiv), 1 (0.4 mmol, 2.0 equiv), [Ir(dtbbpy)(ppy)₂]PF₆ (1.0 mol%), TMEDA (0.4 mmol, 2.0 equiv), 4 Å MS (50 mg), dry MeCN (2 mL), rt, 16 h, under a N₂ atmosphere and 25 W Blue LEDs. Isolated yields are reported.