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Showing 1–2 of 2 results
Advanced filters: Author: Arnaud Dochain Clear advanced filters

  • The products and dynamics in mutual neutralisation of \({{{{\rm{O}}}}_{2}}^{+}\) with O− occurring in atmospheric sprites are unknown. Here, the authors reveal a dissociative two-step mechanism via intermediate Rydberg states and a dependence on the \({{{{\rm{O}}}}_{2}}^{+}\) vibrational state.

    • Mathias Poline
    • Arnaud Dochain
    • Richard D. Thomas
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-9

  • The mutual neutralization of hydronium and hydroxide ions is a reaction of fundamental interest that has recently been implicated in the generation of high concentrations of hydroxyl radicals at the surface of water microdroplets. Using three-dimensional imaging of the coincident neutral products of the reaction of D3O+ and OD−, two competing pathways for OH radical formation have now been experimentally observed.

    • Alon Bogot
    • Mathias Poline
    • Daniel Strasser
    Research
    Nature Chemistry
    Volume: 17, P: 541-546