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Showing 1–3 of 3 results
Advanced filters: Author: Baokun Qiao Clear advanced filters
  • Asymmetric dearomative photocycloaddition has emerged as a transformative strategy for the enantioselective construction of complex three-dimensional molecular architectures from simple planar aromatic precursors. Herein, the authors report the direct asymmetric dearomative photocycloaddition involving electron-deficient isoquinolines.

    • Jingjing Huo
    • Songwei Yang
    • Zhiyong Jiang
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-10
  • Enantioselective substitution reactions of racemic alkyl halides are inherently limited by the specificity of their stereochemical course (SN1 or SN2). Here, the authors report a radical coupling strategy for the enantioselective aminoalkylation of α-bromoketones for modular, highly enantioselective Csp3−Csp3 bond formation.

    • Jiangtao Li
    • Manman Kong
    • Zhiyong Jiang
    ResearchOpen Access
    Nature Communications
    Volume: 9, P: 1-9
  • Asymmetric transformations involving abundant chemical feedstocks such as toluene and its derivatives are rather rare. Here, the authors report the radical enantioselective C(sp3) −C(sp3) coupling of activated ketones with toluenes by means of chiral acid catalysis to afford enantioenriched tertiary alcohols.

    • Fuyuan Li
    • Dong Tian
    • Zhiyong Jiang
    ResearchOpen Access
    Nature Communications
    Volume: 10, P: 1-9