A general method for the stereoretentive Pd-catalysed cross-coupling of secondary alkyl azastannatranes and aryl electrophiles is described. This work constitutes the first example of a stereoretentive cross-coupling reaction using an unactivated, isolable, optically active organometallic nucleophile.
- Ling Li
- Chao-Yuan Wang
- Mark R. Biscoe
