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Showing 1–12 of 12 results
Advanced filters: Author: Charles B. Musgrave Clear advanced filters

  • Polymers cross-linked with dynamic bonds can switch the phase from solid to fluid upon stimulus but return quickly to the solid state once the stimulus is removed. Here the authors report a light triggered permanent solid to fluid transition at room temperature with inherent spatiotemporal control in either direction

    • Brady T. Worrell
    • Matthew K. McBride
    • Christopher N. Bowman
    ResearchOpen Access
    Nature Communications
    Volume: 9, P: 1-7

  • A fundamental mechanism for singlet fission, a process that may govern instances of multi-exciton generation, has yet to be described. Sophisticated calculations now show that singlet fission in pentacene proceeds through the conversion of a photoexcited state into a dark state of multi-exciton character that subsequently splits into two triplets.

    • Paul M. Zimmerman
    • Zhiyong Zhang
    • Charles B. Musgrave
    Research
    Nature Chemistry
    Volume: 2, P: 648-652

  • Electrochemically mediated CO2 capture is a developing alternative to conventional temperature and pressure-swing processes but faces challenges of stability and selectivity. Here, authors develop redox-tunable Brønsted acids to enable electrochemical CO2 capture in nonvolatile organic solvents.

    • Xing Li
    • Charles B. Musgrave III
    • Yayuan Liu
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-14

  • Selective electrochemical CO2 reduction (CO2RR) in strong acids remains challenging due to competition with the hydrogen evolution reaction. Now it is reported that peripheral functionalization of immobilized molecular complexes with quaternary ammonium groups can regulate the mass distribution surrounding the active sites, enabling selective CO2RR in strong acids.

    • Qiang Zhang
    • Charles B. Musgrave III
    • Ruquan Ye
    Research
    Nature Synthesis
    Volume: 3, P: 1231-1242

  • While strain engineering via support modification is a powerful strategy to tune catalytic properties, it is complex to control for immobilized molecular complexes. Now the curvature of carbon nanotubes is leveraged to induce strain to metal phthalocyanine complexes and boost their electrocatalytic activity

    • Jianjun Su
    • Charles B. Musgrave III
    • Ruquan Ye
    ResearchOpen Access
    Nature Catalysis
    Volume: 6, P: 818-828

  • Materials databases currently neglect the temperature effect on compound thermodynamics. Here the authors introduce a Gibbs energy descriptor enabling the high-throughput prediction of temperature-dependent thermodynamics across a wide range of compositions and temperatures for inorganic solids.

    • Christopher J. Bartel
    • Samantha L. Millican
    • Aaron M. Holder
    ResearchOpen Access
    Nature Communications
    Volume: 9, P: 1-10

  • Sensitivity to O2 hinders the application of some electrochemically mediated carbon capture technologies under ambient air conditions. Here the authors report electrochemical CO2 capture via non-aqueous proton-coupled electron transfer, employing alkoxides as active sorbents, in which all species involved are highly air stable.

    • Andong Liu
    • Charles B. Musgrave III
    • Yayuan Liu
    Research
    Nature Energy
    Volume: 9, P: 1415-1426