The surface-initiated graft polymerization of covalently bound polymer brushes attached to an sp3 random carbon network backbone structure is demonstrated. Poly(ethyl acrylate) (PEA), poly(4-fluorostyrene) (PFS) and poly(acrylonitrile) (PAN) brushes were grafted from the network backbone polymer poly(hydridocarbyne), 1, illustrating the breadth of reactivity of the network backbone. The grafted polymer brushes significantly change the solubility and surface characteristics of the poly(hydridocarbyne) sp3 random carbon network backbone.
- Jeffrey F Greco
- Patricia A Bianconi