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Showing 1–2 of 2 results
Advanced filters: Author: Jia-Luo Fu Clear advanced filters

  • Both the pyrroloindoline core and N–CF3 moiety hold significant importance in medicinal chemistry. Herein, the authors present a simple approach to assembling such intriguing skeletons from tryptamine-derived isocyanides through a cascade sequence, which includes an oxidative trifluorination and a subsequent halogenative cyclization.

    • Jun-Yunzi Wu
    • Long-Ling Huang
    • Qingjiang Li
    ResearchOpen Access
    Nature Communications
    Volume: 15, P: 1-8

  • The efficient preparation of inherently unstable N-CF3 secondary amines remains a challenge in synthetic chemistry. Herein, the authors present the synthesis of this type of compounds via oxidative fluorination of isocyanides using iodine as the oxidant, silver fluoride as the fluorinating reagent, and tert-butyldimethylsilane as the proton precursor.

    • Jia-Luo Fu
    • Jun-Yunzi Wu
    • Qingjiang Li
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-10