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Showing 1–5 of 5 results
Advanced filters: Author: Jianyou Mao Clear advanced filters

  • Homoenolates and their higher homologs have much potential, albeit largely unrealized, in transition metal catalysis. Here, the authors report the nickel-catalyzed generation of homoenolates, and their higher homologs, via decarbonylation of cyclic anhydrides, which then undergo cross-coupling with alkyl bromides.

    • Tingzhi Lin
    • Yuanyun Gu
    • Jianyou Mao
    ResearchOpen Access
    Nature Communications
    Volume: 11, P: 1-9

  • Molecules with 4 aryl groups attached to a central carbon atom have proven challenging to synthesize despite their attractiveness for a variety of applications. Here the authors report a Pd-catalysed arylation of di- and triarylmethanes, giving a high-yielding route to an array of tetraarylmethanes.

    • Shuguang Zhang
    • Byeong-Seon Kim
    • Patrick J. Walsh
    ResearchOpen Access
    Nature Communications
    Volume: 8, P: 1-8

  • Amines are common targets in synthetic chemistry as they often display biological activity. Here, the authors report a one-pot aminobenzylation of aldehydes with readily available toluenes in presence of a sodium amide derivative and a cesium salt additive generating an array of valuable 1,2-diarylethylamine compounds.

    • Zhiting Wang
    • Zhipeng Zheng
    • Patrick J. Walsh
    ResearchOpen Access
    Nature Communications
    Volume: 9, P: 1-8