Mechanically robust and shape-persistent hollow toroidal polymer microrings have been synthesized directly by thiol-ene photopolymerization of rectangular-shaped monomers with dithiols. The size of the microrings can be tuned by varying the monomer concentration. The resulting structures can encapsulate molecules in their hollow interiors and also serve as scaffolds to template the formation of circular arrays of metal nanoparticles.
- Jiyeong Lee
- Kangkyun Baek
- Kimoon Kim