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Showing 1–2 of 2 results
Advanced filters: Author: Luca Torkowski Clear advanced filters

  • C–H functionalization is a key reaction in organic synthesis. Now a selenoxide reagent has been developed for the formation of arylselenonium salts via C–H functionalization of DNA conjugates with high selectivity. The arylselenonium salts participate in various transformations to forge new C–C and C–X bonds.

    • Eduardo de Pedro Beato
    • Luca Torkowski
    • Tobias Ritter
    ResearchOpen Access
    Nature Chemistry
    Volume: 17, P: 1340-1347

  • 1,3-Disubstituted bicyclo[1.1.1]pentanes are linear bioisosteres for para-substituted benzene rings; however, the lack of practical reagents for the introduction of bicyclopentane currently impedes their application, especially in drug development. Now, stable thianthrenium-based bicyclopentane reagents are reported and their use in O-, N- and C-alkylation reactions demonstrated.

    • Eva Maria Alvarez
    • Zibo Bai
    • Tobias Ritter
    ResearchOpen Access
    Nature Synthesis
    Volume: 2, P: 548-556