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Showing 1–6 of 6 results
Advanced filters: Author: Rob Ameloot Clear advanced filters

  • This work introduces the kinetic selectivity achievable in nanoporous crystals into the field of chemical sensors, opening the door for selective VOC detection in health, safety, and environmental monitoring

    • Aleksander Matavž
    • Margot F. K. Verstreken
    • Rob Ameloot
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-8

  • The intrinsically hybrid nature of metal–organic frameworks (MOFs) — microporous crystalline solids composed of metal ions and organic ligands — has been exploited to grow thin MOF films at the aqueous–organic interface of a biphasic reaction mixture. These materials exhibit selective permeability and can also be obtained as hollow capsules that have potential as microreactors.

    • Rob Ameloot
    • Frederik Vermoortele
    • Dirk E. De Vos
    Research
    Nature Chemistry
    Volume: 3, P: 382-387

  • The low dielectric constants and high porosity of MOFs are of interest for applications in electronics and sensors, but patterning techniques for these materials are in their infancy. Here, direct X-ray and electron-beam lithography at sub-50-nm resolution are reported that leave porosity and crystallinity intact.

    • Min Tu
    • Benzheng Xia
    • Rob Ameloot
    Research
    Nature Materials
    Volume: 20, P: 93-99

  • Insulating materials combining a high mechanical stability, a low dielectric constant and the ability to completely fill narrow gaps are essential to fabricate interconnects for future high-performance chips. Here, the authors integrate zeolitic imidazolate frameworks as ultra-low-k dielectrics within a 90 nm pitch metallization layer via selective vapor-based conversion of metal oxide films.

    • Mikhail Krishtab
    • Ivo Stassen
    • Rob Ameloot
    ResearchOpen Access
    Nature Communications
    Volume: 10, P: 1-9

  • The authors show that thin films of microporous metal–organic frameworks can be deposited on a broad range of substrates and on high-aspect-ratio features by means of chemical vapour deposition.

    • Ivo Stassen
    • Mark Styles
    • Rob Ameloot
    Research
    Nature Materials
    Volume: 15, P: 304-310