As the aluminum analogues of alkenes, dialumenes have the potential to lose one or two π-bonding electrons, forming dialumene-derived radical cations or dications, but they are challenging to isolate due to intrinsic electron deficiency. Here, the authors present the synthesis of a stable aluminum-centered radical cation and dication.
- Xufang Liu
- Arseni Kostenko
- Shigeyoshi Inoue
