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Showing 1–2 of 2 results
Advanced filters: Author: Suvajit Koley Clear advanced filters

  • Trifluoromethyl arenes are amongst the commonly encountered fluorinated substructures in pharmaceutical, agrochemical, and material sciences. Herein, the authors report a deoxytrifluoromethylation/aromatization strategy that converts readily available cyclohexan(en)one substrate into highly substituted trifluoromethyl arenes.

    • Pankaj Bhattarai
    • Mohammed K. Abd El-Gaber
    • Ryan A. Altman
    ResearchOpen Access
    Nature Communications
    Volume: 15, P: 1-9

  • A catalytic para-selective alkylation reaction connects C–H functionalization and decarboxylative coupling strategies using simple bases to trap a previously hidden intermediate. This reaction exploits an ‘inverted sequence’ that forms the C–C bond prior to C–H bond cleavage and provides a new entry into C–H functionalization reactions.

    • Francisco de Azambuja
    • Ming-Hsiu Yang
    • Ryan A. Altman
    Research
    Nature Chemistry
    Volume: 12, P: 489-496