Selective conversion of methane into value-added chemicals is a promising approach for utilization of hydrocarbon sources. Here the authors develop dimeric copper centers supported on graphitic carbon nitride (denoted as Cu2@C3N4) with >10% conversion and >98% selectivity toward methyl oxygenates in both thermo- and photo- catalytic reactions.
- Pengfei Xie
- Jing Ding
- Chao Wang