Entropic ligands can dramatically improve the solubility of nanocrystals, but it is not known how these mixed ligand systems actually arrange and interact on a particle surface. Here, the authors use advanced solid-state NMR techniques to understand the partitioning and dynamics of entropic mixed ligand shells on CdSe nanocrystals, and relate this molecular picture to the particles’ macroscopic solubility behavior.
- Zhenfeng Pang
- Jun Zhang
- Xiaogang Peng