Our recent studies on the anionic polymerization achieved using flow microreactors are reviewed. Using flow microreactors, with features such as precise temperature control, rapid mixing, and precise time control, otherwise impossible polymer synthesis reactions can occur. Some typical examples synthesizing polymers with reactive functional groups and heterotelechelic polymers are described. This review also highlights the in-line analyses of the polymer living end, helping a deeper insights of the reaction and its conditions. The continuous operation of the flow microreactors demonstrated their potential for industrial applications.
- Aiichiro Nagaki
- Yosuke Ashikari
