A new surface-directed crystallization mechanism enabled by the chemical and structural inhomogeneity of the glass substrate through self-limited nanocrystallization of glassy phase was proposed and demonstrated. Benefiting from the intricate interplays between nanoscale force and heterogeneous surface, the strategy offers new opportunities in the large-scale development of various metastable crystallization products and also serves practical purpose.
- Shifeng Zhou
- Binbin Zheng
- Jianrong Qiu