Abstract
MANY infra-red spectra of metal complexes have been examined in the 2–15μ region, but until now very few co-ordination compounds have been studied in the cæsium bromide region in which some metal-ligand atom-stretching frequencies are expected1. Furthermore, no correlation between the frequency of this vibration and the nature of the metal has been found2.
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References
Bertin, Nagagawa, Mizushima, Lane, and Quagliano, J. Amer. Chem. Soc., 80, 525 (1958).
Barrow, Krueger, and Basolo, J. Inorg. Nuclear Chem., 2, 340 (1956). Cf. Cotton, “The Infrared Spectra of Transitional Metal Complexes”, in Lewis, and Wilkins, “Modern Co-ordination Chemistry” (Interscience Pub., Inc., New York, 1960).
Irving, and Williams, J. Chem. Soc., 3192 (1953).
Ciampolini, Paoletti, and Sacconi (unpublished work). Poulsen, and Bjerrum, Acta Chem. Scand., 9, 1407 (1955).
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SACCONI, L., SABATINI, A. The ‘Irving–Williams’ Order in the Metal-ligand Stretching Frequencies of Some Metal Hydrazine Complexes. Nature 186, 549 (1960). https://doi.org/10.1038/186549a0
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DOI: https://doi.org/10.1038/186549a0
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