Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Letter
  • Published:

Influence of Hydrostatic Pressure on Orientation in Electrophilic Aromatic Substitutions

Abstract

M. G. GONIKBERG et al.1–3 have recently found that at high pressures the attack of phenyl radicals on tertiary butyl benzene yields an appreciably higher proportion of the sterically strained 2-phenyl isomer than it does at atmospheric pressure.

This is a preview of subscription content, access via your institution

Access options

Buy this article

USD 39.95

Prices may be subject to local taxes which are calculated during checkout

Similar content being viewed by others

References

  1. Gonikberg, M. G., Prokhorova, N. I., and Litvin, E., Izv. Akad. Nauk. S.S.S.R. (Otd. Khim. Nauk.), No. 8, 1495 (1962).

  2. Gonikberg, M. G., Prokhorova, N. I., and Litvin, E., Doklady Akad. Nauk. S.S.S.R., 148, 105 (1963).

    CAS  Google Scholar 

  3. Gonikberg, M. G., Zhur. Fiz. Khim., 37, 477 (1963).

    CAS  Google Scholar 

  4. Coillet, D. W., and Hamann, S. D., Trans. Farad. Soc., 57, 2231 (1961).

    Article  CAS  Google Scholar 

  5. Olah, G. A., and Kuhn, S. J., J. Amer. Chem. Soc., 84, 3684 (1962).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

COILLET, D., HAMANN, S. Influence of Hydrostatic Pressure on Orientation in Electrophilic Aromatic Substitutions. Nature 200, 166–167 (1963). https://doi.org/10.1038/200166b0

Download citation

  • Issue date:

  • DOI: https://doi.org/10.1038/200166b0

This article is cited by

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing