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A New Organic Radical Reaction involving No Free Valence

Nature volume 200, page 256 (1963)Cite this article

Abstract

THE discovery of a fundamentally new type of organic radical reactions involving no unpaired electron has been already reported1–3. The work recorded here was concerned with a reaction between a free radical, triacetone-aminoxyl and the Grignard reagent. The reaction proceeding with conservation of free valence yielded a new organic free radical with a hydroxyl group:

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References

  1. Rozantzev, E. G., Mamedova, Yu. G., and Neiman, M. B., Izv. Akad. Nauk SSSR, Otdel. Khim. Nauk, No. 12, 2250 (1962).

  2. Neiman, M. B., Rozantzev, E. G., and Mamedova, Yu. G., Nature, 196, 472 (1962).

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  3. Rozantzev, E. G., and Papko, R. A., Izv. Akad. Nauk SSSR, Otdel. Khim. Nauk, No. 3 (1963).

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences, Moscow

    M. B. NEIMAN, E. G. ROZANTZEV & YU. G. MAMEDOVA

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  1. M. B. NEIMAN
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  2. E. G. ROZANTZEV
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  3. YU. G. MAMEDOVA
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NEIMAN, M., ROZANTZEV, E. & MAMEDOVA, Y. A New Organic Radical Reaction involving No Free Valence. Nature 200, 256 (1963). https://doi.org/10.1038/200256a0

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