Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Letter
  • Published:

Abiotic Formation of Phosphoric Anhydride Bonds in Dilute Aqueous Conditions

Abstract

DURING some experiments in which sodium dithionite, Na2S2O4, was employed as a reducing agent in aqueous phosphate buffer, it was noticed that the presence of condensed phosphates could be chromatographically detected at the end of each experiment. It was soon verified that sodium dithionite alone was responsible for this phenomenon.

This is a preview of subscription content, access via your institution

Access options

Buy this article

USD 39.95

Prices may be subject to local taxes which are calculated during checkout

Similar content being viewed by others

References

  1. Miller, S. L., and Parris, M., Nature, 204, 1248 (1964).

    Article  ADS  CAS  Google Scholar 

  2. Steinman, G., Lemmon, R. M., and Calvin, M., Proc. US Nat. Acad. Sci., 52, 27 (1964).

    Article  ADS  CAS  Google Scholar 

  3. Beck, A., and Orgel, L. E., Nature, 208, 1000 (1965).

    Article  ADS  CAS  Google Scholar 

  4. Beck, A., and Orgel, L. E., Proc. US Nat. Acad. Sci., 54, 664 (1965).

    Article  ADS  CAS  Google Scholar 

  5. Karl-Kroupa, E., Anal. Chem., 28, 1091 (1956).

    Article  CAS  Google Scholar 

  6. Fuchs, R. J., and Czeck, F. W., Anal. Chem., 35, 769 (1963).

    Article  CAS  Google Scholar 

  7. Chess, W. B., and Bernhart, D. N., Anal. Chem., 31, 1116 (1959).

    Article  CAS  Google Scholar 

  8. Bartlett, G. R., J. Biol. Chem., 234, 466 (1959).

    CAS  Google Scholar 

  9. Latimer, W. M., The Oxidation States of the Elements and Their Potentials in Aqueous Solutions, second ed., 77 (Prentice–Hall, New Jersey, 1952).

    Google Scholar 

  10. Rittmann, A., Volcanoes and Their Activity (John Wiley, New York, 1962).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

GABEL, N. Abiotic Formation of Phosphoric Anhydride Bonds in Dilute Aqueous Conditions. Nature 218, 354 (1968). https://doi.org/10.1038/218354a0

Download citation

  • Received:

  • Revised:

  • Issue date:

  • DOI: https://doi.org/10.1038/218354a0

This article is cited by

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing