Abstract
WE report here the first successful optical resolution experiments using low temperature chromatography, for which we used the tris-acetylacetonato (acac) complexes of Al(III) and Fe(III). Since the apparently unsuccessful attempts to resolve Fe(oxalate)3− at −30 °C on starch1, only room temperature experiments have been reported (for example, refs 2–4).
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on SpringerLink
- Instant access to the full article PDF.
USD 39.95
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Krebs, H., and Schumacher, W., Chem. Ber., 99, 1341–1348 (1966).
Boyle, P. H., Q. Rev., 25, 323–341 (1971).
Dotsevi, G., Sogah, Y., and Cram, D. J., J. Am. chem. Soc., 97, 1259–1261 (1975).
Souter, R. W., J. Chromat., 108, 265–275 (1975).
IUPAC Information Bulletin, 33, 68–69 (1968).
Norden, B., and Jonas, I., Inorg. nucl. Chem. Lett., in the press (1976).
Cahn, R. S., Ingold, C., and Prelog, V., Angew. Chem., 78, 413–442 (1966).
Nelander, B., and Norden, B., Chem. Phys. Lett., 28, 384–388 (1974).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
JONAS, I., NORDEN, B. Optical resolution by chromatography at low temperature. Nature 258, 597 (1975). https://doi.org/10.1038/258597a0
Received:
Accepted:
Published:
Issue date:
DOI: https://doi.org/10.1038/258597a0
This article is cited by
-
Benzomorphan alkaloids: Natural peptidomimetics of opioid peptide pharmacophores
Letters in Peptide Science (1995)
-
Simultaneous determination of toxic heavy metals in Metformin hydrochloride using reversed-phase high-performance liquid chromatography
Fresenius' Journal of Analytical Chemistry (1993)
