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Rapid polymer transport in concentrated solutions through the formation of ordered structures

Abstract

Our previous finding that high molecular weight polymers in certain systems can be transported with an unexpectedly high apparent ‘diffusion’ rate in the presence of a concentrated second polymer has been shown to be due to the formation and movement of organized macroscopic structures in an otherwise convection-free solution. The structures are not formed as part of a normal phase separation but will dissipate with time. Their formation may be understood by recently developed principles of nonlinear nonequilibrium thermodynamics.

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Preston, B., Laurent, T., Comper, W. et al. Rapid polymer transport in concentrated solutions through the formation of ordered structures. Nature 287, 499–503 (1980). https://doi.org/10.1038/287499a0

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