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Organic Chemistry

Molecules in quarantine

Intermediate compounds are often produced during a chemical reaction, but they are too short-lived to be easily observed. It seems that a molecular pyramid can persuade them to stick around for a little longer.

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Figure 1: Trapping reactive intermediates.

References

  1. Dong, V. M., Fiedler, D., Carl, B., Bergman, R. G. & Raymond, K. N. J. Am. Chem. Soc. 128, 14464–14465 (2006).

    Article  CAS  Google Scholar 

  2. Fiedler, D., Bergman, R. G. & Raymond, K. N. Angew. Chem. Int. Edn 43, 6748–6751 (2004).

    Article  CAS  Google Scholar 

  3. Iwasawa, T., Mann, E. & Rebek, J. Jr J. Am. Chem. Soc. 128, 9308–9309 (2006).

    Article  CAS  Google Scholar 

  4. Yoshizawa, M., Kuskawa, T., Fujita, M. & Yamaguchi, K. J. Am. Chem. Soc. 122, 6311–6312 (2000).

    Article  CAS  Google Scholar 

  5. Yoshizawa, M., Tamura, M. & Fujita, M. Science 312, 251–254 (2006).

    Article  CAS  ADS  Google Scholar 

  6. MacGillivary, L. R. & Atwood, J. L. Nature 389, 469–472 (1997).

  7. Hof, F., Craig, S. L., Nuckolls, J. & Rebek, J. Jr Angew. Chem. Int. Edn 41, 1488–1508 (2002).

    Article  CAS  Google Scholar 

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Rebek, J. Molecules in quarantine. Nature 444, 557 (2006). https://doi.org/10.1038/444557a

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