Extended Data Figure 8: Comparison of the TRXSS data measured with excitations at two different wavelengths, 310 and 267 nm. | Nature

Extended Data Figure 8: Comparison of the TRXSS data measured with excitations at two different wavelengths, 310 and 267 nm.

From: Direct observation of bond formation in solution with femtosecond X-ray scattering

Extended Data Figure 8: Comparison of the TRXSS data measured with excitations at two different wavelengths, 310 and 267 nm.

a, Right singular vectors obtained from the SVD analysis for the 310 nm (left) and 267 nm (right) excitations. For both cases, the right singular vectors were fitted by only one kinetic component and their extracted time constants are almost identical to each other. b, Difference scattering curves at 100 ps time delay measured with excitations at 310 nm (black) and 267 nm (red). The error bar at each data point indicates the standard error determined from 50 independent measurements. The two curves are identical to each other within the experimental error. This similarity between the kinetics and the shapes of the difference scattering curves indicates negligible contribution from dimer excitation for both 310 and 267 nm excitations.

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