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This additivity implies the parallel orientation of a pair of dissimilar monomer units.
Even if the estimated γ0 is multiplied by a constant P, the calculated curve does not coincide with the observed curve. It probably suggests that P varies with φ; i.e., P=P(φ).
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Saito, H., Matsuura, M., Okada, T. et al. Short-Range Order in a Miscible Polymer Blend. Polym J 21, 357–360 (1989). https://doi.org/10.1295/polymj.21.357
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DOI: https://doi.org/10.1295/polymj.21.357
