Abstract
In order to improve the fracture toughness and mechanical properties of TGAP/DAP system, modified polyetherimide was incorporated in the tetrafunctional epoxy resin system. During the hydrolysis of polyetherimide, the formation of new carboxylic acid and amide increased gradually with increasing the hydrolysis time of neat polyetherimide. As the content of modified polyetherimide was increased up to 10 wt%, the mechanical property of cured epoxy resin was significantly increased compared with that of the unmodified polyetherimide system. In TGAP/DAP/MPEI system, the number and size of dispersed phase within cured epoxy resin were gradually decreased with the increase of the hydrolysis time of polyetherimide. In addition, investigation of the relationship between the morphology and the mechanical properties was also undertaken in TGAP/DAP/MPEI system.
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References
C. E. Browning, Polym. Eng. Sci., 18, 16 (1978).
E. L. McKangue, J. D. Reynold, and J. E. Haskin, J. Appl. Polym. Sci., 22, 1643 (1978).
A. Apicella, L. Nicolais, G. Astarita, and E. Drioli, Polymer, 20, 1143 (1979).
J. Mijovic, J. Kim, and J. Slaby, J. Appl. Polym. Sci., 29, 144 (1984).
A. F. Yee and R. A. Pearson, “Toughening Mechanism in Elastomer Modified Epoxy Resins,” NASACR-3718 (1983).
and NASA-3852 (1984).
A. V. Pocius, W. J. Schultz, and R. E. Adam, “The Proceedings of the Adhesion Society,” Washington, D.C., 1986, p 4.
L. T. Manzione and J. K. Gillham, J. Appl. Polym. Sci., 26, 889 (1981).
L. T. Manzione and J. K. Gillham, J. Appl. Polym. Sci., 26, 907 (1981).
H. N. Nae, S. Reich, and Z. Nir, “Rubber-Modified Thermoset Resins,” American Chemical Society, Washington, D.C., 1984, p 218.
R. S. Bauer, The Proceedings of 18th International SAMPE Technical Conference, October 7—9, 1986, pp 510—519.
L. C. Chan, J. K. Gillham, A. J. Kinlock, and S. J. Shaw, “Rubber-Modified Thermoset Resins,” American Chemical Society, Washington, D.C., 1984, p 261.
S. Henry and Y. Hsich, The Proceedings of 34th International SAMPE Symposium, May 8—11, 1989, p 884.
H. Younhing, W. Huigong, and Z. Xiping, The Proceedings of 34th International SAMPE Symposium, May 8—11, 1989, p 875.
B. L. Riley, V8/GR. MK5 Air Frame Composite Application, in Proceedings of the 2nd International Conference on Fiber Reinforced Composites, London Institute of Mechanical Engineering, Publication C33/86, 1986, p 153.
R. S. Rayhava, The Proceedings of 28th National SAMPE Conference, Vol. 28, 1983, p 367.
R. S. Bauer, A. G. Filippov, L. M. Sclandt, and W. V. Breitigana, The Proceedings of 32nd International SAMPE Symposium, April 6—9, 1987, pp 1104—1113.
R. S. Bauer, “The Proceedings of 33rd International SAMPE Symposium,” March 7—10, 1988, pp 1385—1393.
R. S. Bauer, “The Proceedings of 34th International SAMPE Symposium,” May 7—11, 1989, pp 1889—1900.
L. M. Schlaudt, R. S. Bauer, and C. A. Blackburn, “The Proceedings of 34th International SAMPE Symposium,” May 8—11, 1989, pp 917—928.
J. S. Shim, W. Lee, and J. Jang, Polym. J., 23, 903 (1991).
J. S. Shim, W. Lee, and J. Jang, Polym. J., 23, 911 (1991).
J. S. Shim, W. Lee, and J. Jang, Polym. Bull., 25, 661 (1991).
J. S. Shim, W. Lee, and J. Jang, Polym. Bull., 25, 669 (1991).
M. S. Selton, P. T. McGrail, J. A. Peacock, S. P. Wilknson, R. A. Crick, M. Davies, and G. Almen, The Proceedings of 19th International SAMPE Technical Conference, Vol. 19, 1987, p 700.
D. A. Shimp, F. A. Hudock, and W. S. Boho, The Proceedings of 18th International SAMPE Technical Conference, Vol. 18, 1986, p 851.
P. Steiner, J. M. Browne, M. T. Blain, and J. M. McKillen, The Proceedings of 18th International SAMPE Technical Conference, Vol. 18, 1986, p 851.
H. D. Stenzenberger, P. Koenig, M. Herzog, W. Romer, S. Pierce, and M. Canning, “The proceedings of 32nd International SAMPE Symposium,” Vol. 32, 1987, p 44.
A. Okamoto, Polym. Eng. Sci., 23, 222 (1983).
E. M. Yokgitis, N. S. Eiss Jr., C. Tran, G. L. Wilkes, and J. E. McGrath, in “Epoxy Resins and Composites I,” K. Dusek, Ed., Spnnger Verlag Berlin 1986 pp 79—109.
C. A. May, “Epoxy Resin Chemistry and Technology,” C. A. May, Ed., Marcel Dekker, Inc., New York and Basel, 1988.
A. R. Siebert and C. K. Riew, Paper presented at the 161st ACS Meeting, Organic Coating Plastic Division, Los Angeles, CA, 1971.
R. A. Pearson and A. F. Yee, Polym. Mater. Sci. Eng. Prepr., 316 (1983).
C. A. Finch, S. Hashemi, and A. J. Kinloch, Polym. Commun., 28, 322 (1987).
J. M. Barton, in “Epoxy Resins and Composites I,” K. Dusek, Ed., Springer Verlag, Berlin, 1986, pp 111—154.
R. E. Fines and J. P. Bartolomucci, in “Engineering Plastics,” N. J. Epel, J. M. Margolis, S. Newman, and R. B. Seymour, Ed., ASM Internatlonal, New York N.Y., 1988, pp 156—158.
C. B. Bucknall, “Toughened Plastics,” Applied Science, London, 1977.
A. J. Kinloch and D. L. Hunston, J. Mater. Sci. Lett., 6, 137 (1987).
S. C. Kunsi-Douglass, P. W. R. Beaumont, and M. F. Ashby, J. Mater. Sci., 15, 1109 (1980).
R. B. Bauer and H. D. Stenzenberger, “The Proceedings of 34th International SAMPE Symposium,” May 8—11, 1989, p 899.
W. D. Bascom, R. Y. Ting, R. J. Moulton, C. K. Riew, and A. R. Siebert, J. Mater. Sci., 16, 2697 (1981).
M. S. Sefton, P. T. McGrail, and J. A. Peacock, “The Proceedings of 32nd International SAMPE Symposium,” May, 1987, p 700.
A. Okamoto, Poym. Eng. Sci., 23, 222 (1983).
L. T. Mazione and J. K. Gillham, Paper presented at the 178th ACS National Meeting, Organic Coating Plastic Divisions, Washington, D.C., 1979.
C. K. Riew, E. H. Rowe, and A. R. Siebert, in “Toughness and Brittleness of Plastics,” ACS Advance in Chemistry Series, 154, 326 (1976).
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Jang, J., Lee, W. Polyetherimide-Modified High Performance Epoxy Resin. Polym J 26, 513–525 (1994). https://doi.org/10.1295/polymj.26.513
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DOI: https://doi.org/10.1295/polymj.26.513
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