Abstract
Inverse gas chromatography was used to measure partial molar heats of mixing ΔH1∞ of several solutes on poly(propylene oxide) rubber. Flory-Huggins interaction parameter interaction parameters χ12 and its enthalpic and entropic contributions were also calculated at 354.1, 359.0, and 363.0 K. Polymer solubility parameters were deduced by the method of DiPaola-Baranyi from Flory-Huggins χ12 interaction parameters. Solubility parameters δ1 for the solutes were also reported.
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References
J. H. Hildebrand and R. L. Scott, “The Solubility of Non-electrolytes,” 3rd ed, Reinhold, New York, N.Y., 1950.
J. E. Guillet, J. Macromol. Sci. Chem., 4, 1669 (1970).
DiPaola-Baranyi and J. E. Guillet, Macromolecules, 11, 288 (1978).
D. Patterson, Rubber Chem. Technol., 40, 1 (1967).
P. J. Flory, “Principles of Polymer Chemistry,” Cornell University Press, Ithaca, New York, N.Y. 1953.
G. D. Price, J. E. Guillet, and H. H. Purnell, J. Chromatogr., 369, 273 (1986).
BF Goodrich Elastomer & Latex Division, Technical Data (1987).
A. T. James and A. J. P. Martin, Biochem. J., 50, 679 (1952).
P. J. Flory, J. Chem. Phys., 9, 660 (1941).
M. L. Huggins, J. Chem. Phys., 9, 440 (1941).
J. H. Dymond and E. B. Smith “The Virial Coefficients of Pure Gases and Mixtures,” Clarendon Press, Oxford, 1980.
M. L. Mcglashan and D. J. B. Potter, Proc. R. Soc. London, Ser. A, 267, 468 (1962).
E. A. Guggenhein and C. J. Normal, J. Chem. Phys., 42, 375 (1965).
J. A. Riddick and W. B. Bunger, “Techniques of Chemistry,” Vol. II, Organic Solvents, J. Willey & Sons, New York, N.Y., 1970.
R. A. Orwoll and P. J. Flory, J. Am. Chem. Soc., 89, 6814 (1967).
J. Timmermams, “Physicochemical Constants of Pure Organic Compounds,” Elsevier, New York, N.Y., Vol. I, 1950 and
J. Timmermams, “Physicochemical Constants of Pure Organic Compounds,” Elsevier, New York, N.Y., Vol. II, 1965.
R. D. Newman and J. M. J. Prausnitz, J. Paint Technol., 45, 34 (1973).
D. W. Van Krevelen and P. J. Hoftyzer, “Propertres of Polymers, Correlations with Chemical Structure,” Elsevier, Amsterdam, 1972.
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Morales, E., Acosta, J. Polymer Solubility Parameters of Poly(propylene oxide) Rubber from Inverse Gas Chromatography Measurements. Polym J 28, 127–130 (1996). https://doi.org/10.1295/polymj.28.127
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DOI: https://doi.org/10.1295/polymj.28.127
