Abstract
Electroactive shape-memory hydro-epoxy/carbon black composites are investigated in this study. The thermomechanical and the shape-memory properties of these composites are characterized using dynamic mechanical analysis and U-type shape-memory tests. These results indicate that the glass transition temperature (Tg) of the composites decreases first and then increases slightly as the carbon black content increases. The storage modulus at high temperatures increases as the carbon black content increases. The percolation threshold of the electroactive shape-memory hydro-epoxy composite is lower than that for many other composites. Because of the low percolation threshold, the electroactive shape-memory hydro-epoxy composite exhibits excellent shape-memory property. The sample filled with 1.9 wt% carbon black can recover nearly 100% of its original shape in only a few minutes under an applied voltage of 200 V.
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References
Sokolowski, W. M. & Tan, S. C. Advanced self-deployable structures for space applications. J. Spacecr. Rocket. 44, 750–754 (2007).
Santo, L. Shape memory epoxy foams: New materials for aerospace applications. Mater. Sci. Forum 706–709, 165–172 (2012).
Lan, X., Liu, Y. J., Lv, H. B., Wang, X. H., Leng, J. S. & Du, S. Y. Fiber reinforced shape-memory polymer composite and its application in a deployable hinge. Smart Mater. Struct. 18, 024002 (2009).
Guo, B. C., Chen, Y. W., Lei, Y. D., Zhang, L. Q., Zhou, W. Y., Rabie, A. B. M. & Zhao, J. Q. Biobased poly(propylene sebacate) as shape memory polymer with tunable switching temperature for potential biomedical applications. Biomacromolecules 12, 1312–1321 (2011).
Nanfelt, M. R., Marolf, A. J., Powers, B. E. & Monnet, E. Use of a dacron shape-memory intravascular coil to achieve slow, progressive occlusion of the jugular vein in dogs. Veter. Surg. 40, 853–860 (2011).
Singhal, P., Wilson, T. S. & Maitland, D. J. Controlling the physical properties of random network based shape memory polymer foams. Mater. Res. Soc. Symp. Proc. 1274, 43–49 (2010).
Yakacki, C. M., Shandas, R., Lanning, C., Rech, B., Eckstein, A. & Gall, K. Unconstrained recovery characterization of shape-memory polymer networks for cardiovascular applications. Biomaterials 28, 2255–2263 (2007).
Yu, K., Liu, Y. J. & Leng, J. S. Conductive shape memory polymer composite incorporated with hybrid fillers: electrical, mechanical, and shape memory properties. J. Intell. Mater. Syst. Struct. 22, 369–379 (2011).
Lan, X., Liu, Y. J. & Leng, J. S. Electrically conductive shape-memory polymer filled with Ni powder chains. Proc. SPIE 7287, 72871S (2009).
Leng, J. S., Huang, W. M., Lan, X., Liu, Y. J. & Du, S. Y. Significantly reducing electrical resistivity by forming conductive Ni chains in a polyurethane shape-memory polymer/carbon-black composite. Appl. Phys. Lett. 92, 204101 (2008).
Liu, H. B., Liu, Y. J., Gou, J. H., Leng, J. S. & Du, S. Y. Electroactive shape-memory polymer nanocomposites incorporating carbon nanofiber paper. Int. J. Smart Nano Mater 1, 2–12 (2010).
Jung, Y. C., Goo, N. S. & Jae, W. Electrically conducting shape memory polymer composites for electroactive actuator. Proc. SPIE 5385, 230–234 (2004).
Leng, J. S., Lv, H. B., Liu, Y. J. & Du, S. Y. Conductive nanoparticles in electro activated shape memory polymer sensor and actuator. Proc. SPIE 6391, 693109 (2008).
Leng, J. S., Lan, X., Liu, Y. J. & Du, S. Y. Electroactive thermoset shape memory polymer nanocomposite filled with nanocarbon powders. Smart Mater. Struct. 18, 074003 (2009).
Sahoo, N. G., Jung, Y. C., Yoo, H. J. & Cho, J. W. Influence of carbon nanotubes and polypyrrole on the thermal, mechanical and electroactive shape-memory properties of polyurethane nanocomposites. Compos. Sci. Technol. 67, 1920–1929 (2007).
Lv, H. B., Yu, K., Sun, S. H., Liu, Y. J. & Leng, J. S. Mechanical and shape-memory behavior of shape-memory polymer composites with hybrid fillers. Polym. Int. 59, 766–771 (2010).
Zhang, H., Zhang, Z., Friedrich, K. & Eger, C. Property improvements of in situ epoxy nanocomposites with reduced interparticle distance at high nanosilica content. Acta Mater. 54, 1833–1842 (2006).
Via, M. D., King, J. A., Keith, J. M. & Bogucki, G. R. Electrical conductivity modeling of carbon black/polycarbonate, carbon nanotube/polycarbonate, and exfoliated graphite nanoplatelet/polycarbonate composites. J. Appl. Polym. Sci. 124, 182–189 (2012).
Yu, C. R., Wu, D. M., Liu, Y., Qiao, H., Yu, Z. Z., Dasari, A., Du, X. S. & Mai, Y. W. Electrical and dielectric properties of polypropylene nanocomposites based on carbon nanotubes and barium titanate nanoparticles. Compos. Sci. Technol. 71, 1706–1712 (2011).
Sun, X., Jin, J., Wang, X., Cai, D. & Song, M. Conductive behaviour and self-conductance characteristic of carbon nanotubes/functionalized graphene hybrid films. J. Nanosci. Nanotechnol. 11, 5075–5082 (2011).
Chen, D. Q. & Chen, G. H. The conductive property of polyurethane/expanded graphite powder composite foams. J. Reinf. Plast. Compos. 30, 757–761 (2011).
Rios, P. F., Ophir, A., Kenig, S., Efrati, R., Zonder, L. & Popovitz-Biro, R. Impact of injection-molding processing parameters on the electrical, mechanical, and thermal properties of thermoplastic/carbon nanotube nanocomposites. J. Appl. Polym. Sci. 120, 70–78 (2011).
Acknowledgements
This work was supported by the Doctorate Foundation of Northwestern Polytechnical University and the Northwestern Polytechnical University Foundation for Fundamental Research (No. NPU-FFR-201047).
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Wei, K., Zhu, G., Tang, Y. et al. Electroactive shape-memory effects of hydro-epoxy/carbon black composites. Polym J 45, 671–675 (2013). https://doi.org/10.1038/pj.2012.185
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DOI: https://doi.org/10.1038/pj.2012.185
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