Table 2 Exemplified thermodynamic constraints of olefin depolymerization on dodecane as a model compound under different conditions
From: Leveraging mechanochemistry for sustainable polymer degradation
Reaction | \(\Delta {H}_{{{{{{\rm{f}}}}}}}^{0}\)/kJ mol−1 | \(\Delta {S}_{{{{{{\rm{f}}}}}}}^{0}\)/J mol−1 K−1 | \(\Delta {G}_{{{{{{\rm{f}}}}}}}^{0}\)/kJ mol−1 | T/°C |
|---|---|---|---|---|
| 77.6 | 100.6 | 47.6 | 25 |
| 77.6 | 100.6 | −0.1 | 500 |
| −48.1 | −29.22 | −39.4 | 25 |
| −101.2 | −10.7 | −98.0 | 25 |
| 447.3 | 770.62 | 217.7 | 25 |
| 447.3 | 770.62 | 5.7 | 300 |
