Table 2 1H and 13C chemical shift assignments of the sample SD2 recorded in D2O at 500 MHz and 70 °C
Residue | Nucleus | Chemical shifts (ppm) a | |||||
|---|---|---|---|---|---|---|---|
1 | 2 | 3 | 4 | 5 | 6 | ||
D | 1H | 4.53 | 3.49 | 4.20 | 4.15 | 4.02 | 3.90 |
β-d-Galp-3,4 Pyr-(1→ | 13C | 103.3 | 74.2 | 79.5 | 75.6 | 74.0 | 61.7 |
E | 1H | 4.46 | 3.49 | 4.20 | 4.15 | 4.22 | 4.19 – 4.02 |
→6)-β-d-Galp 3,4 Pyr(1→ | 13C | 103.1 | 74.2 | 79.5 | 75.6 | 73.0 | 69.8 |
Pyr S | 1H | 1.60 | |||||
13C | 177.9 | 108.7 | 24.3 | ||||
H1’a | H1’b | H2 | H3’a | H3’b | |||
1-Gro | 1H | 3.99 | 3.70 | 3.94 | 3.68 | 3.60 | |
13C | 72.0 | 72.0 | 71.6 | 63.4 | 63.4 | ||
