Table 1 Glass composition and initial dissolution rate, r0, of some common silicate glasses.
From: Aqueous alteration of silicate glass: state of knowledge and perspectives
ISG | SON68 | Albite glass | Basaltic glass | Obsidian | Roman glass | Soda-lime | Pyrex | Bioglass 45S5 | E | |
|---|---|---|---|---|---|---|---|---|---|---|
Glass composition in mol% | ||||||||||
SiO2 | 60.1 | 52.7 | 75 | 61.6 | 83 | 72.4 | 72.9 | 81.0 | 46.1 | 57.0 |
B2O3 | 16.0 | 14.0 | 13.0 | 6.1 | ||||||
Al2O3 | 3.8 | 3.4 | 12.5 | 10.9 | 8.2 | 1.1 | 1.0 | 2.0 | 8.8 | |
P2O5 | 0.1 | 2.6 | ||||||||
Fe2O3 | 3.0 | 5.1 | 0.6 | 0.1 | ||||||
Na2O | 12.6 | 11.4 | 12.5 | 3.2 | 3.9 | 19.4 | 12.3 | 4.0 | 24.4 | 0.6 |
Li2O | 4.6 | 2.5 | ||||||||
K2O | 2.9 | |||||||||
CaO | 5.7 | 5.0 | 14.6 | 1.0 | 5.4 | 7.2 | 26.9 | 19.6 | ||
MgO | 0.3 | 6.6 | 6.5 | |||||||
BaO | 0.3 | |||||||||
SrO | 0.2 | |||||||||
ZrO2 | 1.7 | 1.5 | ||||||||
MoO3 | 0.9 | |||||||||
TiO2 | 0.1 | 0.4 | ||||||||
∑RE2O3 | 0.9 | |||||||||
Other | 2.0 | 2.0 | 1.5 | <1 | <1 | |||||
Initial dissolution rate r0 in g·m−2·d−1 in the (T, pH) conditions given in the reference (Ref.) | ||||||||||
T (°C), pH | 90 9 | 90 9 | 90 9 | 90 8.4 | 157 7a | 90 9.5 | 87 9a | 90 7a | 37 7a | 90 9 |
r0 | 8.2 | 0.3 | 0.26 | 0.8 | 6 × 10−3 | 5.9 | 7.7 | 0.5 | 45 | 4.6 |
Ref. | np | |||||||||
Initial dissolution rate r0 in g·m−2·d−1 recalculated at 90 °C pH 9 from the measured value | ||||||||||
r0,calc at 90 °C, pH 9 | 8.2 3.2 | 0.3 | 0.26 | 1.4 | 2 × 10−3 | 2.5 | 23 | 3 | >8000 | 4.6 |