Table 1 Glass composition and initial dissolution rate, r0, of some common silicate glasses.

From: Aqueous alteration of silicate glass: state of knowledge and perspectives

 

ISG

SON68

Albite glass

Basaltic glass

Obsidian

Roman glass

Soda-lime

Pyrex

Bioglass 45S5

E

Glass composition in mol%

SiO2

60.1

52.7

75

61.6

83

72.4

72.9

81.0

46.1

57.0

B2O3

16.0

14.0

     

13.0

 

6.1

Al2O3

3.8

3.4

12.5

10.9

8.2

1.1

1.0

2.0

 

8.8

P2O5

 

0.1

      

2.6

 

Fe2O3

 

3.0

 

5.1

0.6

0.1

    

Na2O

12.6

11.4

12.5

3.2

3.9

19.4

12.3

4.0

24.4

0.6

Li2O

 

4.6

 

2.5

      

K2O

    

2.9

     

CaO

5.7

5.0

 

14.6

1.0

5.4

7.2

 

26.9

19.6

MgO

    

0.3

 

6.6

  

6.5

BaO

 

0.3

        

SrO

 

0.2

        

ZrO2

1.7

1.5

        

MoO3

 

0.9

        

TiO2

    

0.1

    

0.4

∑RE2O3

 

0.9

        

Other

 

2.0

 

2.0

 

1.5

<1

  

<1

Initial dissolution rate r0 in g·m−2·d−1 in the (T, pH) conditions given in the reference (Ref.)

T (°C), pH

90

9

90

9

90

9

90

8.4

157

7a

90

9.5

87

9a

90

7a

37

7a

90

9

r0

8.2

0.3

0.26

0.8

6 × 10−3

5.9

7.7

0.5

45

4.6

Ref.

60

256

166

256

222

257

245

257

257

258

np

Initial dissolution rate r0 in g·m−2·d−1 recalculated at 90 °C pH 9 from the measured value

r0,calc at 90 °C, pH 9

8.2

3.2

0.3

0.26

1.4

2 × 10−3

2.5

23

3

>8000

4.6

  1. For the sake of comparison, r0 has been given at 90 °C pH90°C 9. For each study (T, pH) conditions of r0 measurement are given. If they differed from the selected conditions, r0 was calculated at 90 °C, pH 9 with Eq. (4). If Ea and η were not available, r0,calc was determined with Ea = 60 kJ·mol−1 and =0.4.
  2. np not published, RE rare earth elements.
  3. apH given at room temperature. Uncertainty on r0 is ~50%, except for bioglass and obsidian, for which r0,calc was estimated from small amounts of data and under temperature and pH conditions far from the reference.