Table 1 Electrochemical information obtained from potentiodynamic polarisation, electrochemical impedance spectroscopy, and linear polarisation resistance measurements of AA2024-T3 samples exposed to inhibitor-containing solutions

From: Laying the experimental foundation for corrosion inhibitor discovery through machine learning

Inhibitor

jcorr

Ecorr

Ebr

Z2h

Z24h

\({\left.{R}_{{\rm {p}}}\right\vert }_{24{\rm {h}}}\)

\(\left\langle {R}_{{\rm {p}}}\right\rangle\)

 

(nA cm−2)

(mV)

(mV)

(kΩ cm2)

(kΩ cm2)

(kΩ cm2)

(kΩ cm2)

Uninhibited (0.1 M NaCl)

604 (±108)

−620 (±12)

−486 (±2)

14 (±0)

14 (±3)

11 (±1)

11 (±1)

Benzotriazole

216 (±38)

−500 (±3)

−475 (±4)

79 (±31)

107 (±48)

100 (±44)

94 (±43)

2,5-dimercapto-1,3,4 thiadiazole

3822 (±399)

−604 (±6)

−479 (±6)

51 (±18)

3 (±0)

3 (±0)

16 (±4)

2-mercaptobenzimidazole

79 (±18)

−523 (±6)

−496 (±8)

80 (±30)

265 (±80)

253 (±85)

207 (±66)

2-mercaptobenzoate

261 (±65)

−527 (±16)

−472 (±19)

130 (±50)

38 (±16)

53 (±21)

135 (±7)

Sodium acetate

396 (±54)

−563 (±14)

−473 (±13)

16 (±2)

16 (±1)

13 (±2)

15 (±1)

Sodium mercaptoacetate

57 (±13)

−572 (±25)

−435 (±34)

203 (±47)

203 (±64)

561 (±191)

555 (±205)

Ammonium pyrollidinedithiocarbamate

38 (±4)

−636 (±14)

−488 (±14)

346 (±34)

480 (±106)

335 (±73)

356 (±173)

  1. Corrosion current density jcorr, corrosion Ecorr and breakdown Ebr potentials vs. AgAgCl, impedance modulus values Z observed at 10−2 Hz evaluated for 2 and 24 h, linear polarisation resistance Rp evaluated at 24 h and the time-weighted average of the measurements \(\left\langle {R}_{{\rm {p}}}\right\rangle\) are presented.