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Supramolecular crystals for hydrogen storage

Adsorbents for efficient hydrogen storage require both a high gravimetric and volumetric storage capacity. A catenation strategy guided by hydrogen bonding is now demonstrated for the construction of supramolecular crystals with both high volumetric and large gravimetric surface areas, robustness and ideal pore diameters, which contribute to their good performance for hydrogen storage.

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Fig. 1: Interpenetration analysis and the formation of seven-fold catenated superstructures.

References

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This is a summary of: Zhang, R. et al. Balancing volumetric and gravimetric capacity for hydrogen in supramolecular crystals. Nat. Chem. https://doi.org/10.1038/s41557-024-01622-w (2024).

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Supramolecular crystals for hydrogen storage. Nat. Chem. 16, 1941–1942 (2024). https://doi.org/10.1038/s41557-024-01661-3

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