Extended Data Fig. 5: Pressure dependence of kobs and the values of activation volumes obtained for the *ET and *CPET reactions. | Nature Chemistry

Extended Data Fig. 5: Pressure dependence of kobs and the values of activation volumes obtained for the *ET and *CPET reactions.

From: High-pressure pump–probe experiments reveal the mechanism of excited-state proton-coupled electron transfer and a shift from stepwise to concerted pathways

Extended Data Fig. 5: Pressure dependence of kobs and the values of activation volumes obtained for the *ET and *CPET reactions.

The values of kobs at each pressure were obtained as described in Extended Data Figs. 3 and 4. The activation volumes for *ET and *CPET reactions were determined based on the pressure dependence of ln(kobs-ET) and kobs-CPET) as shown in Fig. 6b and d.

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