Extended Data Fig. 1: Gram-scale preparation and synthetic transformation of stereogenic-at-P(V) compounds. | Nature Chemistry

Extended Data Fig. 1: Gram-scale preparation and synthetic transformation of stereogenic-at-P(V) compounds.

From: Stepwise-controllable catalytic asymmetric Atherton–Todd reaction to access diverse P(V)-stereogenic compounds

Extended Data Fig. 1: Gram-scale preparation and synthetic transformation of stereogenic-at-P(V) compounds.The alternative text for this image may have been generated using AI.

a, Gram-scale preparations. b, Transformation of SPOs (A) into diverse chiral phosphine ligands and catalysts. See general procedure VIII/X in Supplementary Information 7.2. *The product E13 was recrystallized once from a DCM/n-hexane mixture, affording optically pure compound in >99% ee with 86% yield.

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