Fig. 4: Molecular mass and structure of epifadin.

a, MS/MS spectrum of intact epifadin (HR-ESI(+) TOF MS) indicates a mass of intact epifadin of 964.4472 Da. b, Purple moiety elucidated by NMR and MS, orange moiety by NMR and tetramic acid moiety (black, inferred from genetic, 1D-NMR, 2D-NMR and HR-MS data in accordance with detailed MS mechanistic considerations; the structure is not depicted in its keto-tautomeric form).