Fig. 2: Deracemization of biaryl 1a.
From: Redox-powered autonomous directional C–C bond rotation under enzyme control
a, Optimization of deracemization of 1a: (±)-1a (10 mM), ADH 291, NADP, NADPH oxidase (YcnD (60 μM)), NaPi (100 mM), DMSO (10% v:v), H3N·BH3 (100 mM, 10 equiv.), O2 (air), ee analysis performed by high-performance liquid chromatography at 24 h. b, Yield and ee of 1a over time for conditions in entry 5; error bars are derived from triplicate reactions, in which the error given is the sample standard deviation between the triplicates.
