Extended Data Fig. 6: Statistical analysis of bond length and bond angle from the HRTEM along the [\(2\bar{1}\bar{1}0\)] zone axis. | Nature

Extended Data Fig. 6: Statistical analysis of bond length and bond angle from the HRTEM along the [\(2\bar{1}\bar{1}0\)] zone axis.

From: Synthesis of bulk hexagonal diamond

Extended Data Fig. 6: Statistical analysis of bond length and bond angle from the HRTEM along the [
                        
                          
                        
                        $$2\bar{1}\bar{1}0$$
                        
                          
                            2
                            
                              
                                1
                              
                              ¯
                            
                            
                              
                                1
                              
                              ¯
                            
                            0
                          
                        
                      ] zone axis.

A shorter (red) bond length 1.50 ± 0.08 Å along the (0001) direction and a longer (blue) bond length 1.58 ± 0.05 Å along the [0, 8, \(\bar{8}\), \(\bar{3}\)] direction was retrieved from 20 pairs and 18 pairs C–C distance, respectively, using the Laplacian of Gaussian blob detection algorithm implemented in the scikit-image package. A relatively larger bond angle distribution with an average of 112.1 ± 2.8° was obtained. To verify the accuracy of atomic position identification, the d-spacing values of the (\(01\bar{1}0\)) and (0001) planes (labelled with yellow dashed lines) were analysed to be 2.175 ± 0.063 Å and 2.080 ± 0.030 Å, averaged from the distances between 36 and 32 atom pairs, respectively, which match the d-spacing values from XRD measurement very well.

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