Extended Data Fig. 2: Additional 29 substrates as extended scope (deaminative functionalization).
From: Direct deaminative functionalization with N-nitroamines
Isolated yields. a1H NMR yield. See Supplementary Information Sections 4–6 for full experimental details. General halogenation conditions: amine (0.5 mmol), SOBr2 (1.25 mmol) as a bromine source, HNO3 (2.0 equiv.), DMAP (2.5 equiv.), DCE (5.0 mL), 70 °C, 1 h; amine (0.5 mmol), KI (2.0 mmol) as an iodine source, HNO3 (6.0 equiv.), DCE (5.0 mL), 70 °C, 1 h. Nuc, nucleophiles; Ph, phenyl; Tf, trifluoromethanesulfonyl; Sandm., Sandmeyer conditions; n.d., not detected.
