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a, 3 ps at LCLS (Pande et al.14). b - c, 10 ps, 30 ps and 80 ps at EuXFEL. e, 100 ps at APS (Jung et al. 33). The extrapolated maps were calculated from 13,722, 13,142, 13,014, 12,889 and 13,214 extrapolated structure factors for the 3 ps to 100 ps time delays, respectively.