Table 3 Dissolved Inorganic Carbon (DIC) distributions and fluxes in Tagus estuary. Equations are polynomial equations used to fit the data from DIC versus salinity for each sampling transects. All equations have p < 0.05. C0 and CS are, respectively, freshwater and seawater DIC concentrations. The flux of freshwater DIC is defined as (Q · C0), whereas the flux of internal DIC is (Q · (CS − C0)) and the estuarine flux is (Q · CS). Q represents the Tagus River flow.

From: Inorganic carbon distribution and CO2 fluxes in a large European estuary (Tagus, Portugal)

Season

Sampling dates

DIC (µmol kg−1) as a function of S

r2

C0 a (µmol kg−1)

CS b (µmol kg−1)

Freshwater DIC Flux (106 mol C d−1)

Internal DIC Flux (106 mol C d−1)

Estuarine DIC Flux (106 mol C d−1)

Spring

May 2000

43.1 S + 1540.7

0.774

1540.7

1540.7

51.0

0

51.0

Winter

March 2001

−29.2 S2 + 230.0 S + 1110.5

0.628

1110.5

2151.2

179.2

167.9

347.1

Summer

July 2001

23.5 · S + 1815.0

0.903

1815.0

1815.0

16.6

0

16.6

Summer

June 2002

−1.5 S2 + 63.4 S + 2481.5

0.527

2481.5

4243.2

17.8

12.6

30.5

Spring

May 2003

14.4 S + 1818.4

0.948

1818.4

1818.4

37.6

0

37.6

Winter

February 2004

0.7 S2 + 6.7 · S + 1832.7

0.602

1832.7

1445.8

42.5

−9.0

33.5

Spring

May 2006

−1.3 · S2 + 59.6 S + 1704.1

0.629

1704.1

3018.7

18.9

14.6

33.5

Autumn

November 2006

21.2 S + 2010.5

0.739

2010.5

2010.5

136.4

0

136.4

Annual mean values (Tg C yr−1)

0.27

0.10

0.37

  1. aDIC concentration where the polynomial equation intersects the y-intercept (or the concentration at zero salinity)
  2. bDIC concentration where the tangent at the marine end-member crosses the y-intercept