Table 2 13C NMR (100 MHz) data for compounds 1–6 in CDCl3 (δ in ppm).
Pos. | 1 | 2 | 3 | 4 | 5 | 6 |
|---|---|---|---|---|---|---|
1 | 175.8, C | 174.9, C | 175.4, C | 175.6, C | 175.8, C | 174.8, C |
3 | 50.7, CH | 50.7, CH | 50.7, CH | 50.6, CH | 50.8, CH | 50.6, CH |
4 | 52.5, CH | 52.9, CH | 51.6, CH | 51.3, CH | 52.6, CH | 50.6, CH |
5 | 35.2, CH | 35.3, CH | 35.1, CH | 35.2, CH | 35.5, CH | 35.2, CH |
6 | 139.7, C | 139.8, C | 139.8, C | 139.8, C | 139.7, C | 140.2, C |
7 | 125.6, CH | 125.5, CH | 125.6, CH | 125.7, CH | 125.6, CH | 125.4, CH |
8 | 43.2, CH | 43.9, CH | 43.3, CH | 43.6, CH | 44.1, CH | 44.0, CH |
9 | 66.9, C | 65.1, C | 66.4, C | 67.6, C | 67.1, C | 67.5, C |
10 | 48.6, CH2 | 48.1, CH2 | 48.5, CH2 | 48.5, CH2 | 48.7, CH2 | 48.5, CH2 |
11 | 13.3, CH3 | 13.3, CH3 | 13.4, CH3 | 13.4, CH3 | 13.4, CH3 | 13.4, CH3 |
12 | 19.8, CH3 | 19.8, CH3 | 19.8, CH3 | 19.8, CH3 | 19.8, CH3 | 19.8, CH3 |
13 | 124.8, CH | 124.6, CH | 123.8, CH | 124.6, CH | 124.6, CH | 124.8, CH |
14 | 136.7, C | 137.2, C | 137.4, C | 135.2, C | 134.9, C | 135.2, C |
15 | 44.3, CH2 | 44.1, CH2 | 43.9, CH2 | 43.4, CH2 | 43.7, CH2 | 43.9, CH2 |
16 | 35.1, CH | 35.2, CH | 33.8, CH | 33.0, CH | 33.9, CH | 33.5, CH |
17 | 42.1, CH2 | 43.2, CH2 | 38.1, CH2 | 35.1, CH2 | 32.6, CH2 | 33.7, CH2 |
18 | 207.8, C | 204.3, C | 210.2, C | 68.8, CH | 72.2, CH | 71.3, CH |
19 | 38.0, CH2 | 78.1, CH | 74.2, CH | 29.2, CH2 | 78.8, CH | 70.3, CH |
20 | 37.4, CH2 | 42.5, CH2 | 45.6, CH2 | 35.4, CH2 | 42.9, CH2 | 43.5, CH2 |
21 | 208.1, C | 203.3, C | 206.8, C | 211.5, C | 211.2, C | 212.1, C |
22 | 25.0, CH | 25.0, CH | 25.0, CH | 24.9, CH | 24.9, CH | 25.0, CH |
23/24 | 21.4/23.6, CH3 | 21.5/23.6, CH3 | 21.5/23.5, CH3 | 21.5/23.5, CH3 | 21.5/23.6, CH3 | 21.4/23.5, CH3 |
25 | 15.3, CH3 | 15.3, CH3 | 15.6, CH3 | 16.1, CH3 | 16.2, CH3 | 16.1, CH3 |
26 | 67.4, CH2 | 67.3, CH2 | 67.3, CH2 | 68.3, CH2 | 69.1, CH2 | 68.7, CH2 |
27 | — | 56.9, CH3 | — | — | 58.1, CH3 | — |