Table 4 The major terpenoid compositions in transgenic N. tabacum leaves overexpressing SoNEOD, SoCINS,SoSABS, SoLINS, and SoTPS6.

From: Transcriptome and metabolite analyses reveal the complex metabolic genes involved in volatile terpenoid biosynthesis in garden sage (Salvia officinalis)

N

Compound name

Retention time (min.)

Retention time index

Major fragment ions (m/z)

Formula

Molecular Mass (g mol-1)

Terpene Type

% Peak area

W.T

SoNEOD

SoCINS

SoSABS

SoLINS

SoTPS6

1

L-.alpha.-Terpineol

20.607

1144

139,136,121,107,93,81,79

C10H18O

154.2493

Mono

—

—

0.05

—

—

—

2

L-(-)-Nicotine

26.372

1360.5

162,133,119,92,84,51

C10H14N2

162.2316

 

22.49

0.08

—

0.71

—

0.35

3

trans-.beta.-Ionone

30.596

1488

177,159,149,135,133,121,119

C13H20O

192.2973

 

—

—

0.05

0.17

—

—

4

Topanol;Stavox

31.146

1514.

220,205,177,161,145,115,105

C15H24O

220.3505

Sesqui

—

0.04

—

—

0.04

—

5

cis-Carveol

35.519

1226

137,134,123,119,109,105,95

C10H16O

152.2334

Mono

—

—

—

—

0.1

—

6

.alpha.-Campholenal

35.809

1122

137,119,108,81,67

C10H16O

152.2334

Mono

—

0.08

—

0.23

—

—

7

Menthofuran;

36.17

1163

150,108,79,77,39

C10H14O

150.2176

Mono

—

—

0.05

—

—

—

8

α-Bulnesene

45.066

1506

204,189,161,147,135,107,93

C15H24

204.3511

Sesqui

—

—

 

0.22

—

—

9

cis-9-Hexadecenal

45.266

1759

220,149,138,135,124,121,111

C16H30O

238.4088

 

—

—

—

0.33

—

—

10

Triadimefon

45.59

1997

208,181,128,110,85,57,41,29

C14H16ClN3O2

293.749

 

—

—

0.32

—

—

—

11

Cyclooctasiloxane, hexadecamethyl-

45.773

1688

415,401,355,281,221,147,73

C16H48O8Si8

593.2315

 

—

0.29

—

—

1.57

1.04

12

7-Hexadecenal, (Z)-

45.855

2144

220,135,121,111,98,82,67,55

C16H30O

238.4088

 

—

—

1.7

—

—

—

13

β-Elemol

46.067

1547

204,189,161,135,121,107,93

C15H26O

222.3663

Sesqui

0.14

2.33

—

1

—

—

14

(+) Ledol

46.099

1599

204,189,161,122,109,69,43,41

C15H26O

222.3663

Sesqui

—

0.2

0.1

—

0.33

—

15

Ledol

46.367

1600

204,189,161,147,122,109,81,69

C15H26O

222.3663

Sesqui

—

—

0.37

1.22

—

—

16

d-Ledol

46.431

1602

204,189,161,147,133,122,119

C15H26O

222.3663

Sesqui

—

—

—

—

0.51

—

17

Retinol, acetate

46.635

2531

268,253,145,119,105,91,81,43

C22H32O2

328.4883

 

0.32

1.3

—

—

—

—

18

Phytol

46.736

2110

278,196,179,137,123,95,72

C20H40O

296.5310

Diter

—

—

—

0.74

0.36

5.11

19

cis-Phytol

47.331

2114

278,193,179,151,137,123,109

C20H40O

296.5310

Diter

3.19

6.28

6.75

10.84

3.92

—

20

Carveol

48.108

1225

137,134,119,105,93,92,91,77,41

C10H16O

152.2334

Mono

—

—

—

—

0.27

—

21

α-Limonene diepoxide

48.755

1294

137,123,95,79,67

C10H16O2

168.2328

Mono

—

—

—

2.34

 

—

22

Ledol

48.982

1580

204,189,161,135,133,109,107,69

C15H26O

222.3663

Sesqui

—

—

—

0.28

2.22

—

23

Caryophyllene

50.085

1420

204,189,161,133,120,93,79,69

C15H24

204.3511

Sesqui

30.71

31.53

—

45.45

54.04

72.67

24

Isopulegol

50.305

1143

154,136,121,93,81,67

C10H18O

154.2493

Mono

—

0.12

 

—

—

—

25

.alpha.-Guaiene

50.47

1437

204,189,161,147,133,105,93,79

C15H24

204.3511

Diter

—

—

0.57

—

—

—

26

5.beta.,7.beta.H,10.alpha.-Eudesm-11-en-1.alpha.-ol

50.703

1638

222,207,161,137,125,95,81,55

C15H26O

222.3663

Sesqui

—

—

—

—

0.24

—

27

Lycopene

51.348

3949

457,413,347,321,269,203,177

C40H56

536.89

Sesqui

—

—

0.19

0.39

—

—

28

α-Limonene diepoxide

53.194

1294

137,123,95,79,67

C10H16O2

168.2328

Mono

—

—

—

—

0.15

—

29

α-Elemol

53.591

1546

204,189,161,121,107,93,81,59

C15H26O

222.3663

Sesqui

 

0.53

—

—

—

—

30

Triadimenol

53.554

2023

168,128,112,99,70,59,43,41,29

C14H18ClN3O2

295.765

Sesqui

—

—

0.2

—

—

—

31

Squalene

53.568

2833

367,341,299,203,175,161,137

C30H50

410.7180

Triter

—

—

—

—

0.48

—

32

Verbenol

53.994

1130

137,119,94,81,59

C10H16O

152.2334

Sesqui

—

—

—

—

0.1

—

33

Caryophyllene oxide

54.241

1546

220,205,177,161,135,121,93,79

C15H24O

220.3505

Sesqui

—

—

0.09

—

—

—

34

Globulol

54.833

1581

204,149,161,109,82,69,55,43,41

C15H26O

222.3663

Sesqui

—

—

—

—

0.05

—

35

Caryophyllene oxide

58.543

1583

205,177,149,138,109,93,91,79

C15H24O

220.3505

Sesqui

—

—

0.13

—

—

—

36

Dotriacontane

74.491

3200

407,379,337,295,253,225,127

C32H66

450.8664

 

5.48

—

—

—

—

—

37

Trans-Squalene

74.571

2835

341,328,299,203,149,127,81,69

C30H50

410.7180

Triter

—

—

—

0.13

—

1.24

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